scholarly journals Water-soluble polythiophene∕nanocrystalline TiO2 solar cells

2005 ◽  
Vol 86 (15) ◽  
pp. 153501 ◽  
Author(s):  
Qiquan Qiao ◽  
James T. McLeskey
Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1640
Author(s):  
Massimiliano Lanzi ◽  
Debora Quadretti ◽  
Martina Marinelli ◽  
Yasamin Ziai ◽  
Elisabetta Salatelli ◽  
...  

A new side-chain C60-fullerene functionalized thiophene copolymer bearing tributylphosphine-substituted hexylic lateral groups was successfully synthesized by means of a fast and effective post-polymerization reaction on a regioregular ω-alkylbrominated polymeric precursor. The growth of the polymeric intermediate was followed by NMR spectrometry in order to determine the most convenient reaction time. The obtained copolymer was soluble in water and polar solvents and was used as a photoactive layer in single-material organic photovoltaic (OPV) solar cells. The copolymer photovoltaic efficiency was compared with that of an OPV cell containing a water-soluble polythiophenic homopolymer, functionalized with the same tributylphosphine-substituted hexylic side chains, in a blend with a water-soluble C60-fullerene derivative. The use of a water-soluble double-cable copolymer made it possible to enhance the control on the nanomorphology of the active blend, thus reducing phase-segregation phenomena, as well as the macroscale separation between the electron acceptor and donor components. Indeed, the power conversion efficiency of OPV cells based on a single material was higher than that obtained with the classical architecture, involving the presence of two distinct ED and EA materials (PCE: 3.11% vs. 2.29%, respectively). Moreover, the synthetic procedure adopted to obtain single material-based cells is more straightforward and easier than that used for the preparation of the homopolymer-based BHJ solar cell, thus making it possible to completely avoid the long synthetic pathway which is required to prepare water-soluble fullerene derivatives.


2014 ◽  
Vol 554 ◽  
pp. 204-208 ◽  
Author(s):  
Songyi Park ◽  
Min-Kyu Son ◽  
Soo-Kyoung Kim ◽  
Na-Yeong Hong ◽  
Jeong-Yun Song ◽  
...  

2015 ◽  
Vol 4 (1) ◽  
Author(s):  
Divya Jyoti

AbstractA four phase model air/glass/indium doped tin oxide/TiO2 has been studied by modifying Rouard’s model to calculate the final transmittance from TiO2 layer to be used as photoanode in dye-sensitized solar cells. An optical simulation for the reflectance and transmittance has been executed for the constructed nanocrystalline TiO2 films. To validate the theoretical results TiO2 film has been deposited onto indium doped tin oxide (ITO) layer by sol-gel dip coating technique. It has been found that the incident light suffers losses by 5-15% on passage through TiO2 coated ITO layer. Experimentally it has been observed on the basis of efficiency value that meso-nano combination is the best candidate to be used as photoanode in a dye-sensitize solar cell.


2016 ◽  
Vol 6 (21) ◽  
pp. 1601269 ◽  
Author(s):  
Jiyoon Nam ◽  
Youngjoo Lee ◽  
Wonjung Choi ◽  
Chang Su Kim ◽  
Hogyoung Kim ◽  
...  

2019 ◽  
Vol 7 (6) ◽  
pp. 1592-1596 ◽  
Author(s):  
Han Xu ◽  
Zicheng Ding ◽  
Lu Zhang ◽  
Jun Liu ◽  
Junli Hu ◽  
...  

A water-soluble functionalized unconjugated biomass polymer, Cs+-functionalized pectin (PeCs), can be used as cathode interlayer material for polymer solar cells.


2014 ◽  
Vol 118 (30) ◽  
pp. 16995-17000 ◽  
Author(s):  
Seigo Ito ◽  
Soichiro Tanaka ◽  
Kyohei Manabe ◽  
Hitoshi Nishino

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