scholarly journals Solvent mediated interactions close to fluid-fluid phase separation: Microscopic treatment of bridging in a soft-core fluid

2005 ◽  
Vol 122 (8) ◽  
pp. 084513 ◽  
Author(s):  
A. J. Archer ◽  
R. Evans ◽  
R. Roth ◽  
M. Oettel
2007 ◽  
Vol 104 (9) ◽  
pp. 3165-3170 ◽  
Author(s):  
T. Baumgart ◽  
A. T. Hammond ◽  
P. Sengupta ◽  
S. T. Hess ◽  
D. A. Holowka ◽  
...  

1997 ◽  
Vol 499 ◽  
Author(s):  
Francis H. Ree ◽  
James A. Viecelli

ABSTRACTStatistical mechanical studies predict that a chemically reactive system containing species composed of C, H, N, O atoms can exhibit a phase separation into a N2-rich and a N2-poor phase. The present work is concerned with the effect of the fluid phase separation upon addition of F atoms to the system. Our study shows that F atoms mainly appear as a constituent of HF in a N2-poor fluid phase up to a certain pressure beyond which they occur as CF4 in a N2-rich phase and that the phase separation may be abrupt in a thermodynamic sense. The pressure at the phase boundary can occur at about 30 GPa at 3000 K and about 10 GPa to 20 GPa at 1000 K. Some of these ranges may be accessible by present-day experimental high-pressure techniques. We discuss implications of this study to detonation physics.


2013 ◽  
Vol 139 (4) ◽  
pp. 044911 ◽  
Author(s):  
Sutapa Roy ◽  
Subir K. Das

2009 ◽  
Vol 85 (4) ◽  
pp. 45001 ◽  
Author(s):  
A. V. Ivlev ◽  
S. K. Zhdanov ◽  
H. M. Thomas ◽  
G. E. Morfill

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