Room temperature ferromagnetic and ultraviolet optical properties of Co-doped ZnO nanocluster films

2005 ◽  
Vol 97 (10) ◽  
pp. 10D307 ◽  
Author(s):  
J. Antony ◽  
S. Pendyala ◽  
A. Sharma ◽  
X. B. Chen ◽  
J. Morrison ◽  
...  
2009 ◽  
Vol 58 (3) ◽  
pp. 2018
Author(s):  
Cheng Xing-Wang ◽  
Li Xiang ◽  
Gao Yuan-Ling ◽  
Yu Zhou ◽  
Long Xue ◽  
...  

2020 ◽  
Vol 16 (4) ◽  
pp. 655-666
Author(s):  
Mona Rekaby

Objective: The influence of Manganese (Mn2+) and Cobalt (Co2+) ions doping on the optical and magnetic properties of ZnO nanoparticles was studied. Methods: Nanoparticle samples of type ZnO, Zn0.97Mn0.03O, Zn0.96Mn0.03Co0.01O, Zn0.95Mn0.03 Co0.02O, Zn0.93Mn0.03Co0.04O, and Zn0.91Mn0.03Co0.06O were synthesized using the wet chemical coprecipitation method. Results: X-ray powder diffraction (XRD) patterns revealed that the prepared samples exhibited a single phase of hexagonal wurtzite structure without any existence of secondary phases. Transmission electron microscope (TEM) images clarified that Co doping at high concentrations has the ability to alter the morphologies of the samples from spherical shaped nanoparticles (NPS) to nanorods (NRs) shaped particles. The different vibrational modes of the prepared samples were analyzed through Fourier transform infrared (FTIR) measurements. The optical characteristics and structural defects of the samples were studied through Photoluminescence (PL) spectroscopy. PL results clarified that Mn2+ and Co2+ doping quenched the recombination of electron-hole pairs and enhanced the number of point defects relative to the undoped ZnO sample. Magnetic measurements were carried out at room temperature using a vibrating sample magnetometer (VSM). (Mn, Co) co-doped ZnO samples exhibited a ferromagnetic behavior coupled with paramagnetic and weak diamagnetic contributions. Conclusion: Mn2+ and Co2+ doping enhanced the room temperature Ferromagnetic (RTFM) behavior of ZnO. In addition, the signature for antiferromagnetic ordering between the Co ions was revealed. Moreover, a strong correlation between the magnetic and optical behavior of the (Mn, Co) co-doped ZnO was analyzed.


Optik ◽  
2014 ◽  
Vol 125 (10) ◽  
pp. 2361-2364 ◽  
Author(s):  
Huawa Yu ◽  
Huiqing Fan ◽  
Xin Wang ◽  
Jing Wang

2016 ◽  
Vol 43 ◽  
pp. 23-28 ◽  
Author(s):  
Chun Ping Li ◽  
Ge Gao ◽  
Xin Chen

First-principle ultrasoft pseudo potential approach of the plane wave based on density functional theory (DFT) has been used for studying the electronic characterization and optical properties of ZnO and Fe, Co doped ZnO. The results show that the doping impurities change the lattice parameters a little, but bring more changes in the electronic structures. The band gaps are broadened by doping, and the Fermi level accesses to the conduction band which will lead the system to show the character of metallic properties. The dielectric function and absorption peaks are identified and the changes compared to pure ZnO are analyzed in detail.


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