Nondestructive determination of layers producing Franz-Keldysh oscillations appearing in photoreflectance spectra of heterojunction bipolar transistor structures based on their line-shape analysis

2004 ◽  
Vol 96 (4) ◽  
pp. 1967-1974 ◽  
Author(s):  
Hideo Takeuchi ◽  
Yoshitsugu Yamamoto ◽  
Masaaki Nakayama
Keyword(s):  
Shape Analysis ◽  
Line Shape ◽  
Bipolar Transistor ◽  
Heterojunction Bipolar Transistor ◽  
Nondestructive Determination ◽  
Line Shape Analysis

Determination of the Accurate Values of the Rate Constant and Thermodynamic Parameters for the Rotation About the C(sp2)-C(aryl) Bond; Adamantan-1-yl 3-Bromo-2,4,6-trimethylphenyl Ketone

1998 ◽  
Vol 63 (7) ◽  
pp. 955-966
Author(s):  
Eva Přibylová ◽  
Miroslav Holík
Keyword(s):  
Thermodynamic Parameters ◽  
Shape Analysis ◽  
Rate Constants ◽  
Line Shape ◽  
Microsoft Excel ◽  
Hindered Rotation ◽  
H Nmr ◽  
Line Shape Analysis ◽  
Coalescence Temperature

Four programs for the 1H NMR line shape analysis: two commercial - Winkubo (Bruker) and DNMR5 (QCPE 165) and two written in our laboratory - Newton (in Microsoft Excel) and Simtex (in Matlab) have been tested in order to get highly accurate rate constants of the hindered rotation about a single bond. For this purpose four testing criteria were used, two of them were also developed by us. As supplementary determinations the rate constants obtained for the coalescence temperature and for the thermal racemization of chromatographically separated enantiomers were used which fitted well the temperature dependence of the rate constants determined by the line shape analysis. As a test compound adamantan-1-yl 3-bromo-2,4,6-trimethylphenyl ketone was prepared and studied. It was shown that supermodified simplex method used in our algorithm (Simtex), though time consuming, gives the most accurate values of the rate constants and consequently the calculated thermodynamic parameters Ea, ∆H≠, and ∆S≠ lay in relatively narrow confidence intervals.

scholarly journals Determination of Effective Linewidth Using FMR Line Shape Analysis

1997 ◽  
Vol 07 (C1) ◽  
pp. C1-443-C1-444
Author(s):  
A. K. Srivastava ◽  
M. J. Patni ◽  
B. K. Chaturvedi
Keyword(s):  
Shape Analysis ◽  
Line Shape ◽  
Line Shape Analysis
Sign in / Sign up

Export Citation Format

Share Document