Studies on Glass XII. Some New Heat Capacity Data for Organic Glasses. The Entropy and Free Energy of dl‐Lactic Acid

1936 ◽  
Vol 4 (1) ◽  
pp. 64-69 ◽  
Author(s):  
George S. Parks ◽  
S. Benson Thomas ◽  
Donald W. Light
Keyword(s):  
Heat Capacity ◽  
Free Energy ◽  
Lactic Acid ◽  
Heat Capacity Data ◽  
Organic Glasses ◽  
Capacity Data

Development of the room temperature protocol based on room temperature ionic liquids and surfactant ionic liquids for the synthesis of derivatives of 2-amino-thiazoles and thermo-physical analysis of the synthesized derivatives using TGA-DSC.

2020 ◽  
Vol 10 ◽  
Author(s):  
Chandrakant Sarode ◽  
Sachin Yeole ◽  
Ganesh Chaudhari ◽  
Govinda Waghulde ◽  
Gaurav Gupta
Keyword(s):  
Thermal Analysis ◽  
Heat Capacity ◽  
Ionic Liquids ◽  
Specific Heat ◽  
Specific Heat Capacity ◽  
Room Temperature ◽  
Heat Capacity Data ◽  
General Strategy ◽  
Capacity Data ◽  
Derivatives Of

Aims: To develop an efficient protocol, which involves an elegant exploration of the catalytic potential of both the room temperature and surfactant ionic liquids towards the synthesis of biologically important derivatives of 2-aminothiazole. Objective: Specific heat capacity data as a function of temperature for the synthesized 2- aminothiazole derivatives has been advanced by exploring their thermal profiles. Method: The thermal gravimetry analysis and differential scanning calorimetry techniques are used systematically. Results: The present strategy could prove to be a useful general strategy for researchers working in the field of surfactants and surfactant based ionic liquids towards their exploration in organic synthesis. In addition to that, effect of electronic parameters on the melting temperature of the corresponding 2-aminothiazole has been demonstrated with the help of thermal analysis. Specific heat capacity data as a function of temperature for the synthesized 2-aminothiazole derivatives has also been reported. Conclusion: Melting behavior of the synthesized 2-aminothiazole derivatives is to be described on the basis of electronic effects with the help of thermal analysis. Additionally, the specific heat capacity data can be helpful to the chemists, those are engaged in chemical modelling as well as docking studies. Furthermore, the data also helps to determine valuable thermodynamic parameters such as entropy and enthalpy.

scholarly journals Estimating a Stoichiometric Solid’s Gibbs Free Energy Model by Means of a Constrained Evolutionary Strategy

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 471
Author(s):  
Constantino Grau Turuelo ◽  
Sebastian Pinnau ◽  
Cornelia Breitkopf
Keyword(s):  
Heat Capacity ◽  
Free Energy ◽  
Evolutionary Strategy ◽  
Data Sets ◽  
Automatic Data ◽  
Physical Constraints ◽  
Stoichiometric Model ◽  
Covariance Matrix Adaptation ◽  
Dsc Measurements ◽  
Capacity Data

Modeling of thermodynamic properties, like heat capacities for stoichiometric solids, includes the treatment of different sources of data which may be inconsistent and diverse. In this work, an approach based on the covariance matrix adaptation evolution strategy (CMA-ES) is proposed and described as an alternative method for data treatment and fitting with the support of data source dependent weight factors and physical constraints. This is applied to a Gibb’s Free Energy stoichiometric model for different magnesium sulfate hydrates by means of the NASA9 polynomial. Its behavior is proved by: (i) The comparison of the model to other standard methods for different heat capacity data, yielding a more plausible curve at high temperature ranges; (ii) the comparison of the fitted heat capacity values of MgSO4·7H2O against DSC measurements, resulting in a mean relative error of a 0.7% and a normalized root mean square deviation of 1.1%; and (iii) comparing the Van’t Hoff and proposed Stoichiometric model vapor-solid equilibrium curves to different literature data for MgSO4·7H2O, MgSO4·6H2O, and MgSO4·1H2O, resulting in similar equilibrium values, especially for MgSO4·7H2O and MgSO4·6H2O. The results show good agreement with the employed data and confirm this method as a viable alternative for fitting complex physically constrained data sets, while being a potential approach for automatic data fitting of substance data.

Accurate heat capacity data at phase transitions from relaxation calorimetry

Cryogenics ◽  
2010 ◽  
Vol 50 (10) ◽  
pp. 693-699 ◽  
Author(s):  
Hal Suzuki ◽  
Akira Inaba ◽  
Christoph Meingast
Keyword(s):  
Heat Capacity ◽  
Phase Transitions ◽  
Heat Capacity Data ◽  
Relaxation Calorimetry ◽  
Capacity Data

TABLES OF DEBYE FUNCTIONS

1966 ◽  
Vol 44 (1) ◽  
pp. 45-56 ◽  
Author(s):  
Roger Howard ◽  
J. Grindlay
Keyword(s):  
Heat Capacity ◽  
Distribution Function ◽  
Frequency Distribution ◽  
Phonon Frequency ◽  
Heat Capacity Data ◽  
Frequency Distribution Function ◽  
Capacity Data ◽  
Negative Moments

Tables and asymptotic limits of the Debye functions[Formula: see text]are presented for n = 0.5, 1.0, 1.5, 2.0, 2.5. This information may be used to facilitate the calculation of the negative moments of the phonon frequency distribution function from the heat capacity data of crystals.

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