Comparative Calculations of LCAO‐MOs of the Allyl Radical

1957 ◽  
Vol 26 (1) ◽  
pp. 151-156 ◽  
Author(s):  
Jiro Higuchi
Keyword(s):  
Allyl Radical

Mass spectrometric study of allyl radical, allyl bromide and 1,5-hexadiene interactions with oxides; Cobalt suboxide Co3O4

1979 ◽  
Vol 44 (7) ◽  
pp. 2009-2014 ◽  
Author(s):  
Jana Nováková ◽  
Zdeněk Dolejšek
Keyword(s):  
Room Temperature ◽  
Allyl Bromide ◽  
Catalytic Properties ◽  
Mass Spectrometric Study ◽  
Spectrometric Study ◽  
Flow Conditions ◽  
Allyl Radical ◽  
Knudsen Flow ◽  
Thermally Activated ◽  
Radical Interaction

Products of (a) allyl radical interaction with unheated Co3O4, (b) thermally activated 1,5-hexadiene or thermally activated allyl bromide with unheated Co3O4, (c) moderately heated Co3O4 with unheated 1,5-hexadiene or allyl bromide were studied under Knudsen flow conditions. Cobalt suboxide Co3O4, a typical catalyst of deep oxidations yielded acrolein in reaction with allyl radicals as early as at the room temperature of the catalyst. A similar acrolein formation was also observed in the allyl radical interaction with other oxides exhibiting different catalytic properties. It appears that acrolein is in general the primary product of the allyl radical interaction with the oxides. The results are discussed and compared with previous data obtained with MoO3.

scholarly journals Addition of allyl radical to propylene.

1988 ◽  
Vol 31 (6) ◽  
pp. 478-484
Author(s):  
Daisuke NOHARA ◽  
Tomoya SAKAI
Keyword(s):  
Allyl Radical

Synchrotron Photoionization Mass Spectrometry Measurements of Kinetics and Product Formation in the Allyl Radical (H2CCHCH2) Self-Reaction†

2008 ◽  
Vol 112 (39) ◽  
pp. 9366-9373 ◽  
Author(s):  
Talitha M. Selby ◽  
Giovanni Meloni ◽  
Fabien Goulay ◽  
Stephen R. Leone ◽  
Askar Fahr ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Product Formation ◽  
Allyl Radical ◽  
Photoionization Mass Spectrometry

Radiation chemistry of polyethylene. XIV. Allyl radical decay kinetics in different types of polyethylene

1978 ◽  
Vol 16 (3) ◽  
pp. 467-484 ◽  
Author(s):  
V. M. Patel ◽  
G. N. Patel ◽  
N. Gvozdic ◽  
C. S. Hsu ◽  
Malcolm Dole
Keyword(s):  
Radiation Chemistry ◽  
Decay Kinetics ◽  
Allyl Radical ◽  
Radical Decay ◽  
Different Types

High-resolution infrared spectra of jet-cooled allyl radical (CH2–CH–CH2): ν2, ν3, and ν14 C–H stretch vibrations

2002 ◽  
Vol 116 (15) ◽  
pp. 6505-6512 ◽  
Author(s):  
Jia-xiang Han ◽  
Yu. G. Utkin ◽  
Hong-bing Chen ◽  
Neil T. Hunt ◽  
R. F. Curl
Keyword(s):  
High Resolution ◽  
Infrared Spectra ◽  
Allyl Radical
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