Mechanism of the Catalytic Activation of Molecular Hydrogen by Metal Ions

1955 ◽  
Vol 23 (3) ◽  
pp. 605-605 ◽  
Author(s):  
J. Halpern ◽  
E. Peters
Keyword(s):  
Metal Ions ◽  
Molecular Hydrogen ◽  
Catalytic Activation

CATALYTIC ACTIVATION OF HYDROGEN IN AQUEOUS SOLUTION BY THE CHLOROPALLADATE(II) ION

1959 ◽  
Vol 37 (9) ◽  
pp. 1446-1450 ◽  
Author(s):  
J. Halpern ◽  
J. F. Harrod ◽  
P. E. Potter
Keyword(s):  
Aqueous Solution ◽  
Ferric Chloride ◽  
Molecular Hydrogen ◽  
Homogeneous Catalyst ◽  
Rate Law ◽  
Catalytic Activation ◽  
Kinetics Of ◽  
Mechanism Of The Reaction

The kinetics of the reduction of ferric chloride by molecular hydrogen in aqueous solution, in the presence of chloropalladate(II), were examined. The latter acts as a homogeneous catalyst for the reaction. The rate-law was found to be,[Formula: see text]where[Formula: see text]The mechanism of the reaction is discussed.

CATALYTIC ACTIVATION OF MOLECULAR HYDROGEN IN SOLUTION BY CHLORORHODATE(III) COMPLEXES

1959 ◽  
Vol 37 (11) ◽  
pp. 1933-1935 ◽  
Author(s):  
J. F. Harrod ◽  
J. Halpern
Keyword(s):  
Molecular Hydrogen ◽  
Catalytic Activation

not available

scholarly journals Catalytic activation of ethylene C–H bonds on uniform d8 Ir(i) and Ni(ii) cations in zeolites: toward molecular level understanding of ethylene polymerization on heterogeneous catalysts

2019 ◽  
Vol 9 (23) ◽  
pp. 6570-6576 ◽  
Author(s):  
Nicholas R. Jaegers ◽  
Konstantin Khivantsev ◽  
Libor Kovarik ◽  
Daniel W. Klas ◽  
Jian Zhi Hu ◽  
...  
Keyword(s):  
Metal Ions ◽  
Ethylene Polymerization ◽  
Heterogeneous Catalysts ◽  
Molecular Level ◽  
Catalytic Activation

The long-debated intermediates of ethylene polymerization are revealed using uniform d8 metal ions in zeolites.

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