Microwave Spectrum of Chlorine Dioxide. III. Interpretation of the Hyperfine Coupling Constants Obtained in Terms of the Electronic Structure

1962 ◽  
Vol 37 (4) ◽  
pp. 779-784 ◽  
Author(s):  
R. F. Curl
Keyword(s):  
Electronic Structure ◽  
Chlorine Dioxide ◽  
Hyperfine Coupling ◽  
Microwave Spectrum ◽  
Coupling Constants ◽  
Hyperfine Coupling Constants

Electronic Structure of Pseudotetrahedral Copper(II) Schiff Base Complexes

1977 ◽  
Vol 32 (5) ◽  
pp. 551-561 ◽  
Author(s):  
John R. Wasson ◽  
H. Wayne Richardson ◽  
William E. Hatfield
Keyword(s):  
Electronic Structure ◽  
Schiff Base ◽  
Schiff Bases ◽  
Opposite Direction ◽  
Hyperfine Coupling ◽  
Coupling Constants ◽  
Schiff Base Complexes ◽  
Hyperfine Coupling Constants ◽  
Structure Correlations

Copper(II) complexes with the Schiff bases formed by condensing t-butyl-, isopropyl-, cyclohexyl- and diphenylmethylamines with salicylaldehyde and 3-methoxy- and 5-nitrosalicyl-aldehyde have been prepared and characterized. The isotropic nuclear hyperfine coupling constants increase in the order t-butyl < isopropyl < cyclohexyl < diphenylmethyl for the N-substituents in the three series of complexes while isotropic g-values increased in the opposite direction. Spectra structure correlations were examined and discussed.

Sign in / Sign up

Export Citation Format

Share Document