Heat Capacity and Entropy of CuCl2 and CrCl2 from 11° to 300°K. Magnetic Ordering in Linear Chain Crystals

1962 ◽  
Vol 36 (4) ◽  
pp. 979-991 ◽  
Author(s):  
J. W. Stout ◽  
R. C. Chisholm
1984 ◽  
Vol 23 (15) ◽  
pp. 2213-2215 ◽  
Author(s):  
Richard L. Carlin ◽  
Ramon Burriel ◽  
J. A. Rojo ◽  
Fernando Palacio

2001 ◽  
Vol 63 (14) ◽  
Author(s):  
G. Cao ◽  
S. McCall ◽  
Z. X. Zhou ◽  
C. S. Alexander ◽  
J. E. Crow ◽  
...  

One of the main challenges in the field of the molecular materials is the design of molecular-based ferromagnets. My basic strategy along this line consists of assembling ferrimagnetic chains within the crystal lattice in a ferromagnetic fashion. This can be achieved owing to the (almost) limitless flexibility of the molecular chemistry. The chains may be either regular or alternating. Examples of both situations are presented. MnCu(pbaOH) (H 2 O) 3 (pbaOH = 2-hydroxy-1,3-propylenebis(oxamato)) is a regular chain compound ordering ferromagnetically at T e 4.6 K, and MnCu(obbz) . 1H 2 O (obbz = oxamido-N,N'-bis(2-benzoato)) is an alternating chain compound exhibiting a spontaneous magnetization below T e = 14 K. To get information on the mechanism of the magnetic ordering, a broad spectrum of physical techniques is utilized, including magnetic susceptibility and magnetization measurements, EPR spectroscopy and heat capacity data. The perspectives in this new field are outlined.


1973 ◽  
Author(s):  
M. Eibschütz ◽  
R. C. Sherwood ◽  
F. S. L. Hsu ◽  
C. E. Cox ◽  
Hugh C. Wolfe ◽  
...  

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