Proton‐Transfer Studies by Nuclear Magnetic Resonance. I. Diffusion Control in the Reaction of Ammonium Ion in Aqueous Acid

1960 ◽  
Vol 33 (2) ◽  
pp. 547-555 ◽  
Author(s):  
Merle T. Emerson ◽  
Ernest Grunwald ◽  
Robert A. Kromhout
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Proton Transfer ◽  
Ammonium Ion ◽  
Diffusion Control ◽  
Aqueous Acid ◽  
Nuclear Magnetic

Low temperature nuclear magnetic resonance studies of NH4ClO4

1976 ◽  
Vol 54 (3) ◽  
pp. 239-251 ◽  
Author(s):  
R. F. Code ◽  
J. Higinbotham ◽  
A. R. Sharp
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Low Temperature ◽  
Relaxation Times ◽  
Ammonium Ion ◽  
Proton Relaxation ◽  
Spin Conversion ◽  
Type Symmetry ◽  
Symmetry Species ◽  
Nuclear Magnetic

The properties of ammonium perchlorate were investigated in the temperature range between 1.3 and 50 K by nuclear magnetic resonance and relaxation experiments. The observed increase in the proton second moment from its high temperature value of ~ 1.18 G2 to the value of 4.30 G2 below 4.2 K was associated with a characteristic activation energy of ~ 4 × 10−21 J molecule−1 (~ 0.6 kcal mole−1). No evidence could be found for nuclear spin conversion between the symmetry species of the ammonium ion from measurements of the static proton magnetic susceptibility above 1.3 K. An asymptotic analysis of the low temperature proton lineshapes identified the broad wings of the lines with ammonium ions of T type symmetry. Measurements of the proton relaxation times T1 and T1ρ agreed with previous work by others on NH4ClO4, and were similar to observations on other ammonium compounds having low reorientational barriers.

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