Radiation Chemistry of Liquid Sulfur Dioxide. II. Radiation‐Induced Oxidation—Reduction Reactions in Liquid Sulfur Dioxide Solutions of Sulfur Trioxide and Potassium Iodide

1966 ◽  
Vol 45 (10) ◽  
pp. 3594-3598 ◽  
Author(s):  
Walter G. Rothschild
1971 ◽  
Vol 75 (23) ◽  
pp. 3631-3633 ◽  
Author(s):  
Siegfried Schoenherr ◽  
Helmut Seidel ◽  
Walter G. Rothschild

1983 ◽  
Vol 14 (16) ◽  
Author(s):  
A. I. GERSHENVICH ◽  
S. L. TSAREVA ◽  
E. I. POSENCHUK ◽  
V. M. YUR'EV ◽  
A. B. SHELOV

1984 ◽  
Vol 37 (1) ◽  
pp. 191 ◽  
Author(s):  
PJ Mineely ◽  
SA Tariq

The oxidation-reduction reactions of 12 alkali-metal halides with molten potassium pyrosulfate were studied. Chlorides, bromides and iodides of sodium, potassium, rubidium and caesium were found to be oxidized to produce chlorine, bromine and iodine respectively. Sulfur dioxide was found to be the main reduction product. The reactions between chlorides and pyrosulfate were slow and incomplete, whereas reactions of bromides and iodides were fast and complete. The order of the oxidizability (reducing power) of the halides by pyrosulfate, the temperatures, and stoichiometries of the reactions have been determined.


1994 ◽  
Vol 59 (3) ◽  
pp. 549-557
Author(s):  
František Skopal ◽  
Václav Dušek

Theoretical relationships and simplifying conditions have been derived for the feed of two reaction components into a nonisochoric reactor with ideal stirring. The feed of reaction components is controlled by the negative feedback at a constant absorbance of the reaction mixture. The theoretical relationships have been verified using model 2. order oxidation-reduction reactions of Ce(IV)/V(IV) and Fe(III)/V(III) in 1 M sulfuric acid at 20 °C.


1958 ◽  
Vol 19 ◽  
pp. 10-11 ◽  
Author(s):  
Balwant Singh ◽  
Sardul Singh

ChemInform ◽  
2016 ◽  
Vol 47 (29) ◽  
Author(s):  
Daniels Posevins ◽  
Krista Suta ◽  
Maris Turks

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