Absorption Spectra of the Solvated Electron in Polar Liquids: Dependence on Temperature and Composition of Mixtures

1966 ◽  
Vol 44 (6) ◽  
pp. 2297-2305 ◽  
Author(s):  
Shigeyoshi Arai ◽  
Myran C. Sauer
Keyword(s):  
Absorption Spectra ◽  
Solvated Electron ◽  
Polar Liquids

Solvatation des électrons en excès dans les solvants polaires: corrélation entre les valeurs de εmax, W1/2 et EAmax

1990 ◽  
Vol 68 (4) ◽  
pp. 553-557 ◽  
Author(s):  
J.-P. Jay-Gerin ◽  
C. Ferradini
Keyword(s):  
Optical Absorption ◽  
Absorption Spectra ◽  
Extinction Coefficient ◽  
Molar Extinction Coefficient ◽  
Optical Absorption Spectra ◽  
Solvated Electron ◽  
Solvated Electrons ◽  
Half Height

On the basis of data found in the literature, it is shown that a correlation exists between the molar extinction coefficient at the maximum optical absorption of the solvated electron (εmax), its width at half height (W1/2), and the energy corresponding to that maximum (EAmax) Keywords: solvated electrons, polar solvants, optical absorption spectra. [Journal translation]

Absorption spectra of the solvated electron in hydrocarbons

1992 ◽  
Vol 96 (24) ◽  
pp. 9674-9677 ◽  
Author(s):  
H. Abramczyk ◽  
B. Werner ◽  
J. Kroh
Keyword(s):  
Absorption Spectra ◽  
Solvated Electron

ChemInform Abstract: Absorption Spectra of the Solvated Electron in Hydrocarbons

ChemInform ◽  
2010 ◽  
Vol 24 (11) ◽  
pp. no-no
Author(s):  
H. ABRAMCZYK ◽  
B. WERNER ◽  
J. KROH
Keyword(s):  
Absorption Spectra ◽  
Solvated Electron

scholarly journals Optical absorption spectra of solvated electrons in 1-butylamine–water mixed solvents

1995 ◽  
Vol 73 (12) ◽  
pp. 2126-2130 ◽  
Author(s):  
Yixing Zhao ◽  
Gordon R. Freeman
Keyword(s):  
Optical Absorption ◽  
Absorption Spectra ◽  
Pure Water ◽  
Mixed Solvents ◽  
Binary Solvents ◽  
Optical Absorption Spectra ◽  
Solvated Electron ◽  
Solvated Electrons ◽  
Selective Solvation ◽  
Ideal Mixing

The optical absorption spectra of es− in 1-butylamine–water mixed solvents increase smoothly in energy and intensity as the water content is increased, with the exception of a small decrease in intensity on going from 95 to 100 mol% water. At 298 K the value of Gεmax increases from 1.42 × 10−21 m2/16 aJ (8.6 × 103 es−L/100 eV mol cm) in pure 1-butylamine to 8.3 × 10−21 m2/16 aJ (50 × 103 es−L/100 eV mol cm) in pure water, and the value of EAmax increases from 115 zJ (0.72 eV) to 278 zJ (1.74 eV). In the pure amine, if G(es−) = 0.27, then εmax = 5.3 × 10−21 m2/es− (3200 m2/mol). The solvent composition dependences of Gεmax and EAmax indicate little selective solvation of es− by water; this might be due to relatively "ideal" mixing of water and amine in the binary solvents. The temperature coefficient −dEAmax/dT = 0.43 zJ/K in pure 1-butylamine, 0.47 in pure water, and has a minimum of 0.27 in the 50:50 mixture. Keywords: 1-butylamine–water mixed solvents, optical absorption spectra, solvated electron, temperature dependence.

Absorption spectra of a solvated electron in ethers

1991 ◽  
Vol 157 (3) ◽  
pp. 373-379 ◽  
Author(s):  
Halina Abramczyk ◽  
Jerzy Kroh
Keyword(s):  
Absorption Spectra ◽  
Solvated Electron
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