Direct Spectroscopic Evidence of Bound States of H2–Ar Complexes at 100°K

1965 ◽  
Vol 43 (9) ◽  
pp. 3397-3398 ◽  
Author(s):  
A. Kudian ◽  
H. L. Welsh ◽  
A. Watanabe
1965 ◽  
Vol 43 (5) ◽  
pp. 818-828 ◽  
Author(s):  
A. Watanabe ◽  
H. L. Welsh

The pressure-induced infrared absorption of the fundamental band of hydrogen, in the pure gas and in a H2–He mixture, and of deuterium was studied in the temperature range from 18 °K to 77 °K. Path lengths up to 13.6 m at 1 atm or somewhat higher were obtained in a multiple-traversal cell cooled by liquid hydrogen or nitrogen. The binary coefficient [Formula: see text] for hydrogen shows a rise at low temperature, indicating the existence of bound states predicted by theory for the (H2)2 complex. The effect is more pronounced for deuterium. For the H2–He mixture [Formula: see text] decreases monotonically with temperature, thus showing no evidence of bound states for H2–He pairs. Fine structure at the maxima of the pressure-induced band in hydrogen and deuterium gives direct spectroscopic evidence of bound states of (H2)2 and (D2)2 complexes at low temperatures.


1988 ◽  
Vol 102 ◽  
pp. 129-132
Author(s):  
K.L. Baluja ◽  
K. Butler ◽  
J. Le Bourlot ◽  
C.J. Zeippen

SummaryUsing sophisticated computer programs and elaborate physical models, accurate radiative and collisional atomic data of astrophysical interest have been or are being calculated. The cases treated include radiative transitions between bound states in the 2p4and 2s2p5configurations of many ions in the oxygen isoelectronic sequence, the photoionisation of the ground state of neutral iron, the electron impact excitation of the fine-structure forbidden transitions within the 3p3ground configuration of CℓIII, Ar IV and K V, and the mass-production of radiative data for ions in the oxygen and fluorine isoelectronic sequences, as part of the international Opacity Project.


2014 ◽  
Vol 59 (11) ◽  
pp. 1065-1077 ◽  
Author(s):  
A.V. Nesterov ◽  
◽  
V.S. Vasilevsky ◽  
T.P. Kovalenko ◽  
◽  
...  

2019 ◽  
Author(s):  
Joachim Hönes ◽  
Julia Wack ◽  
Katja Schmitz

<div>Spectroscopic evidence is presented to show that NADH in aqueous solution does not exist as a folded/unfolded equilibrium but as a single state. The molecule is folded but without base stacking between dihydronicotinamide and adenine.<br></div>


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