Pulse Radiolysis Studies. VI. The Lifetimes of Aromatic Anions in the Aliphatic Alcohols

1964 ◽  
Vol 41 (7) ◽  
pp. 2190-2194 ◽  
Author(s):  
Shigeyoshi Arai ◽  
Leon M. Dorfman
Keyword(s):  
Pulse Radiolysis ◽  
Aliphatic Alcohols ◽  
Aromatic Anions

Pulse radiolysis studies XI. Protonation reactions of aromatic anions in some aliphatic alcohols

1967 ◽  
Vol 45 (10) ◽  
pp. 1119-1123 ◽  
Author(s):  
Shigeyoshi Arai ◽  
E. L. Tremba ◽  
J. R. Brandon ◽  
Leon M. Dorfman
Keyword(s):  
Rate Constants ◽  
Pulse Radiolysis ◽  
Activation Energies ◽  
Aliphatic Alcohols ◽  
Absolute Rate ◽  
Protonation Reaction ◽  
Exponential Factors ◽  
Aromatic Anions ◽  
Anion Radicals

The protonation reaction of aromatic anion radicals in the aliphatic alcohols, [Formula: see text]has been investigated by the pulse radiolysis method. Activation energies for this reaction have been determined for the anthracenide anion and diphenylide anion in methanol, ethanol, and isopropanol, and for the naphthalenide anion in isopropanol. Absolute rate constants have been determined as well for the phenanthrenide, o-terphenylide, and m-terphenylide anions in isopropanol at 25 °C. The values for the rate constants, activation energies, and the pre-exponential factors are given. Those properties of the system which determine the kinetics are briefly discussed.

Pulse Radiolysis Studies. IV. The Solvated Electron in the Aliphatic Alcohols

1964 ◽  
Vol 41 (4) ◽  
pp. 979-985 ◽  
Author(s):  
Irwin A. Taub ◽  
Douglas A. Harter ◽  
Myran C. Sauer ◽  
Leon M. Dorfman
Keyword(s):  
Pulse Radiolysis ◽  
Aliphatic Alcohols ◽  
Solvated Electron

Pulse radiolysis of polymers in aqueous solution. Kinetics study

1997 ◽  
Vol 94 ◽  
pp. 244-250 ◽  
Author(s):  
I Janik ◽  
P Kujawa ◽  
P Ulanski ◽  
JM Rosiak
Keyword(s):  
Aqueous Solution ◽  
Pulse Radiolysis ◽  
Kinetics Study ◽  
Solution Kinetics
Sign in / Sign up

Export Citation Format

Share Document