The Effect of Substituents on the Dissociation Constants of Carboxylic Acids

James N. Sarmousakis

doi:10.1063/1.1723940

The Effect of Substituents on the Dissociation Constants of Carboxylic Acids

The Journal of Chemical Physics ◽

10.1063/1.1723940 ◽

1944 ◽

Vol 12 (7) ◽

pp. 277-288 ◽

Cited By ~ 13

Author(s):

James N. Sarmousakis

Keyword(s):

Carboxylic Acids ◽

Dissociation Constants ◽

Effect Of Substituents

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Organic acids in hydrothermal solutions; standard molal thermodynamic properties of carboxylic acids and estimates of dissociation constants at high temperatures and pressures

American Journal of Science ◽

10.2475/ajs.295.5.496 ◽

1995 ◽

Vol 295 (5) ◽

pp. 496-580 ◽

Cited By ~ 136

Author(s):

E. L. Shock

Keyword(s):

Thermodynamic Properties ◽

Organic Acids ◽

Carboxylic Acids ◽

High Temperatures ◽

Dissociation Constants ◽

Hydrothermal Solutions

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ChemInform Abstract: CHEMISTRY OF THE BICYCLO(2,2,2)OCTANES PART 15, DISSOCIATION CONSTANTS OF 4-SUBSTITUTED CUBANE-1-CARBOXYLIC ACIDS, EVIDENCE FOR THE FIELD MODEL FOR THE POLAR EFFECT

Chemischer Informationsdienst ◽

10.1002/chin.197438084 ◽

1974 ◽

Vol 5 (38) ◽

pp. no-no

Author(s):

THOMAS W. JUN. COLE ◽

CAROLYN J. MAYERS ◽

LEON M. STOCK

Keyword(s):

Carboxylic Acids ◽

Field Model ◽

Dissociation Constants ◽

Polar Effect

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42. Chemical constitution and the dissociation constants of mono-carboxylic acids. Part I. Some substituted phenylacetic acids

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9340000161 ◽

1934 ◽

pp. 161 ◽

Cited By ~ 67

Author(s):

J. Frederick J. Dippy ◽

Frank R. Williams

Keyword(s):

Carboxylic Acids ◽

Dissociation Constants ◽

Chemical Constitution

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Analysis of the dependence on temperature of the acid dissociation constants for mono-carboxylic acids in water in terms of a two-stage mechanism

Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases ◽

10.1039/f19817702281 ◽

1981 ◽

Vol 77 (9) ◽

pp. 2281 ◽

Cited By ~ 3

Author(s):

Michael J. Blandamer ◽

John Burgess ◽

Philip P. Duce ◽

Ross E. Robertson ◽

John W. M. Scott

Keyword(s):

Carboxylic Acids ◽

Dissociation Constants ◽

Acid Dissociation ◽

Two Stage ◽

Acid Dissociation Constants

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Dissociation constants of water-insoluble carboxylic acids by13C-NMR. pK as of mesobiliverdin-XIIIα and mesobilirubin-XIIIα

Cellular and Molecular Life Sciences ◽

10.1007/bf01969747 ◽

1996 ◽

Vol 52 (6) ◽

pp. 639-642 ◽

Cited By ~ 5

Author(s):

D. A. Lightner ◽

D. L. Holmes ◽

A. F. McDonagh

Keyword(s):

Carboxylic Acids ◽

Dissociation Constants

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The Dissociation Constants of Acids in Salt Solutions. VI. Carbocyclic Carboxylic Acids

Journal of the American Chemical Society ◽

10.1021/ja01104a021 ◽

1953 ◽

Vol 75 (8) ◽

pp. 1854-1856 ◽

Cited By ~ 12

Author(s):

Martin Kilpatrick ◽

Jerome G. Morse

Keyword(s):

Carboxylic Acids ◽

Dissociation Constants ◽

Salt Solutions

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ChemInform Abstract: Solubility, Stability, and Dissociation Constants of (2RS,4R)-2-Substituted Thiazolidine-4-carboxylic Acids in Aqueous Solutions.

ChemInform ◽

10.1002/chin.200017131 ◽

2010 ◽

Vol 31 (17) ◽

pp. no-no

Author(s):

P. Butvin ◽

J. Al-Ja'afreh ◽

J. Svetlik ◽

E. Havranek

Keyword(s):

Aqueous Solutions ◽

Carboxylic Acids ◽

Dissociation Constants

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Some Derivatives of 1-Benzazepine. Part II

Canadian Journal of Chemistry ◽

10.1139/v74-094 ◽

1974 ◽

Vol 52 (4) ◽

pp. 610-615 ◽

Cited By ~ 12

Author(s):

G. R. Birchall ◽

A. H. Rees

Keyword(s):

Carboxylic Acids ◽

Ring Expansion ◽

Hydrazoic Acid ◽

Ring Contraction ◽

Effect Of Substituents ◽

Ring Expansion Reaction ◽

Derivatives Of

We have investigated the ring expansion of some substituted 1,4-naphthoquinones by hydrazoic acid to yield new 1-benzazepine derivatives of the "azatropolone" type. Ring contraction of those products, which are 2,5-dihydro-3-hydroxy-2,5-dioxo-1-benzazepines, gives 4-quinolone-2-carboxylic acids. Some of the reactions of the new benzazepine system were investigated. Attempts to prepare substituted derivatives suitable for making 1-benzazatrop-5-one were not successful.The effect of substituents on the ring expansion reaction is discussed and an anomalous ring expansion to a 2,5-dihydro-4-hydroxy-2,5-dioxo-1-benzazepine is described and explained mechanistically.

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