Measurements of Dielectric Constant and Dipole Moment of Gases by the Beat‐Frequency Method

1948 ◽  
Vol 19 (4) ◽  
pp. 419-425 ◽  
Author(s):  
J. G. Jelatis
1975 ◽  
Vol 30 (3) ◽  
pp. 287-291 ◽  
Author(s):  
I. Gryczyński ◽  
A. Kawski

A variation of the temperature changes the static dielectric constant (ε) and the refractive index (n) of solvents and, in conjunction with the measurement of solvent shifts of absorption and fluorescence maxima, allows the investigation of dipole moment changes of solutes in the excited state. For this purpose, investigations of the temperature dependences of ε and n of some pure and mixed solvents of different polarities have been made. It is found that the excited dipole moments of indole, 1,2-dimethylindole, 2,3-dimethylindole and tryptophan obtained from the shifts of the fluorescence maxima in mixed solvents at high temperatures are in good agreement with those obtained in other ways.


1956 ◽  
Vol 78 (1) ◽  
pp. 44-45 ◽  
Author(s):  
Max T. Rogers ◽  
Richard D. Pruett ◽  
H. Bradford Thompson ◽  
John L. Speirs

2000 ◽  
Vol 32 (6) ◽  
pp. 631-651 ◽  
Author(s):  
Filipe de Brito ◽  
Anelia Gurova ◽  
Carlos Nieto de Castro ◽  
Umesh Mardolcar

1982 ◽  
Vol 60 (18) ◽  
pp. 2398-2402
Author(s):  
Léo Dégrève ◽  
Paulo Roberto Brossi Pelissari ◽  
Maria Marcia Murta

An equation which allows for the determination of the dipole moment and polarizability of polar substances via the dielectric constant of solutions of the substance in nonpolar solvents is tested using different solute–solvent pairs. The results indicate that this equation provides good values of the dipole moment and of the polarizability if the solvent is correctly chosen. [Journal translation]


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