Mass‐Spectrometric Study of Ions in Xe, Kr, Ar, Ne at Pressures up to 40 torr: Termolecular Formation of the Rare‐Gas Molecular Ions. Bond Dissociation Energy of Ar2+ and Ne2+

1967 ◽  
Vol 47 (5) ◽  
pp. 1684-1691 ◽  
Author(s):  
P. Kebarle ◽  
R. M. Haynes ◽  
S. K. Searles
Keyword(s):  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
Mass Spectrometric Study ◽  
Molecular Ions ◽  
Mass Spectrometric ◽  
Rare Gas ◽  
Spectrometric Study ◽  
Bond Dissociation

Mass spectrometric observation and bond dissociation energy of dimolybdenum, Mo2(g)

1978 ◽  
Vol 17 (11) ◽  
pp. 3211-3213 ◽  
Author(s):  
S. K. Gupta ◽  
R. M. Atkins ◽  
K. A. Gingerich
Keyword(s):  
Bond Dissociation Energy ◽  
Dissociation Energy ◽  
Mass Spectrometric ◽  
Bond Dissociation

Compounds of aziadamantane type: Mass spectrometric study

1989 ◽  
Vol 54 (3) ◽  
pp. 691-698 ◽  
Author(s):  
Sergei D. Isaev ◽  
Nataliya F. Karpenko ◽  
Aleksandr G. Yurchenko ◽  
Luděk Vodička ◽  
Valentin I. Kadentsev ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Mass Spectrometric Study ◽  
Nitrogen Molecule ◽  
Molecular Ions ◽  
Mass Spectrometric ◽  
Spectrometric Study ◽  
Molecular Ion ◽  
Mechanism Of Decomposition ◽  
Derivatives Of ◽  
Type Mass

Azi and hydrazi derivatives of adamantane,adamantanone and diamantane were studied by mass spectrometry. The EI spectra of azi derivatives lack completely molecular ions; the presence of abundant dehydroadamantane or dehydrodiamantane ions corresponds to elimination of nitrogen molecule from the molecular ion. Comparison of the EI ionization with photolysis or pyrolysis allowed to deduce some analogies and to suggest the mechanism of decomposition of the molecular ion.

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