A vacuum cell and associated optics for obtaining a single‐reflection infrared spectrum using reflection‐absorption spectroscopy

1974 ◽  
Vol 45 (10) ◽  
pp. 1221-1223 ◽  
Author(s):  
Harland G. Tompkins ◽  
David L. Allara
2015 ◽  
Vol 310 ◽  
pp. 68-71 ◽  
Author(s):  
Jack C. Harms ◽  
Leah C. O’Brien ◽  
Ann Ni ◽  
Bilal Mahkdoom ◽  
James J. O’Brien

1963 ◽  
Vol 36 (1) ◽  
pp. 219-235
Author(s):  
J. J. Shipman ◽  
M. A. Golub

Abstract Infrared absorption spectroscopy has been employed in the past in efforts to determine the nature of the chemical changes which occur in natural rubber during vulcanization. The most prominent change in the infrared spectrum of rubber accompanying vulcanization with sulfur is the appearance of a new absorption band at 10.4 µ. In the spectra of useful soft rubber vulcanizates this band is barely detectable, while in those of hard rubber (ebonite) it is moderately intense. It has not been known whether this band is related in some way to the actual crosslinking reaction or is the result of some noncrosslinking reaction between the rubber and sulfur molecules.


1996 ◽  
Vol 89 (4) ◽  
pp. 1145-1155
Author(s):  
JACQUES WALRAND ◽  
GHISLAIN BLANQUET ◽  
JEAN-FRANCOIS BLAVIER ◽  
HARALD BREDOHL ◽  
IWAN DUBOIS

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