Kinetics of the reaction between oxygen atoms and carbon disulfide

1974 ◽  
Vol 61 (2) ◽  
pp. 704-709 ◽  
Author(s):  
Irene R. Slagle ◽  
James R. Gilbert ◽  
David Gutman
2004 ◽  
Vol 46 (3) ◽  
pp. 424-429
Author(s):  
A. V. Knotko ◽  
A. V. Garshev ◽  
M. N. Pulkin ◽  
V. I. Putlyaev ◽  
S. I. Morozov

ChemInform ◽  
1990 ◽  
Vol 21 (33) ◽  
Author(s):  
I. R. SLAGLE ◽  
J. R. BERNHARDT ◽  
D. GUTMAN ◽  
M. A. HANNING-LEE ◽  
M. J. PILLING
Keyword(s):  

1976 ◽  
Vol 8 (4) ◽  
pp. 408-409 ◽  
Author(s):  
S. V. Belokonev ◽  
G. T. Glichev ◽  
A. T. Serkov

2020 ◽  
Vol 54 (9) ◽  
pp. 095208 ◽  
Author(s):  
A S Morillo-Candas ◽  
B L M Klarenaar ◽  
C Amoedo ◽  
V Guerra ◽  
O Guaitella

The kinetics of the reaction between oxygen atoms and cyanogen have been studied in a capacity flow reactor at temperatures between 570 and 687 °K. The concentration of CN radicals was measured by electronic absorption spectroscopy. This work confirms the previously proposed mechanism (part II). The initial step has a rate constant of k 1 = 2∙5 (± 0∙3) x 10 13 exp ( – 11000±2000/ RT ) cm 3 mole –1 s –1 . CN radicals are removed mainly by reactions (4) and (2) for which k 4 = 6∙3 (±3∙5) x 10 13 exp (–2400±700/ RT ) cm 3 mole –1 s –1 and k 2 = 4∙4 (±2∙0) x 10 12 cm 3 mole –1 s –1 . CN+O = CO+N, (4) CN+O 2 = NCO+O. (2) The rates of reaction of CN with NO and NH 3 were also measured; for CH 4 and H 2 limiting values were obtained.


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