Spectra and structure of small ring compounds. XXXI Microwave, Raman and infrared spectra, conformation, dipole moment, and quadrupole coupling constants of 2‐oxazoline

1974 ◽  
Vol 61 (1) ◽  
pp. 253-262 ◽  
Author(s):  
J. R. Durig ◽  
S. Riethmiller ◽  
Y. S. Li
1967 ◽  
Vol 1 (9) ◽  
pp. 379-381 ◽  
Author(s):  
G.L. Blackman ◽  
R.D. Brown ◽  
F.R. Burden ◽  
J.E. Kent

The gas-phase paramagnetic resonance spectrum of NF in the J = 2 rotational level of the 1 ∆ state has been studied, and the dipole moment in this state is found to be 0.37 ± 0.60D. The rotational constant previously determined from the electronic spectrum is shown to be consistent with the electron resonance results, and the 14 N quadrupole coupling constant e 2 qQ is 4.1 ± 0.2 MHz. The hyperfine coupling constants of the 14 N and 19 F nuclei are + 109.92 ± 0.14 and +758.06 ± 0.23 MHz respectively.


Sign in / Sign up

Export Citation Format

Share Document