Partial structure factors in the long wavelength limit for binary liquid mixtures of argon‐krypton and krypton‐xenon

1974 ◽  
Vol 61 (1) ◽  
pp. 126-128 ◽  
Author(s):  
E. D. Crozier ◽  
S. P. McAlister ◽  
R. Turner
1989 ◽  
Vol 44 (9) ◽  
pp. 793-800 ◽  
Author(s):  
L. J. Gallego ◽  
J. A. Somoza ◽  
M. Silbert

Abstract The simplified random phase approximation Bhatia-Young model has been used to evaluate the properties of mixing and the concentration fluctuations of the binary liquid mixtures of TKEBS with cyclohcxane. carbon tetrachloride and benzene. At this level of description the details of the potentials are not important; only the values of the long-wavelength limit of the average effective ordering pair potential and its temperature derivative are required. In the three mixtures the constituent molecules are assumed to be globular in shape.


The model of conformal solutions, introduced to study the thermodynamics of liquid mixtures by Longuet-Higgins, is used to calculate the partial structure factors S ij ( q ) of a binary liquid. Explicit expressions are given, in terms of the pair interaction and the radial distribution function for the reference liquid, for the number-concentration structure factors of the mixture. Results are also obtained for transport properties, in particular for interdiffusion and thermal diffusion ratio. Finally some relevant experiments are proposed.


1978 ◽  
Vol 8 (1) ◽  
pp. 45-54 ◽  
Author(s):  
G. Cubiotti ◽  
G. Maisano ◽  
P. Migliardo ◽  
F. Wanderlingh

1980 ◽  
Vol 41 (C8) ◽  
pp. C8-586-C8-589
Author(s):  
M. Favre-Bonte ◽  
J. C. Joud ◽  
P. Hicter ◽  
P. Desre

2019 ◽  
Author(s):  
Samson Semenovich Kutateladze ◽  
G.I. Bobrovich ◽  
I. I. Gogonin ◽  
N.N. Mamontova ◽  
V.N. Moskvicheva

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