Detailed balance in chemical kinetics as a consequence of microscopic reversibility

1974 ◽  
Vol 60 (4) ◽  
pp. 1214-1222 ◽  
Author(s):  
R. K. Boyd
Keyword(s):  
Chemical Kinetics ◽  
Detailed Balance ◽  
Microscopic Reversibility

Detailed Balance and Microscopic Reversibility

1964 ◽  
Vol 40 (10) ◽  
pp. 3124-3124 ◽  
Author(s):  
Frederick P. Boynton
Keyword(s):  
Detailed Balance ◽  
Microscopic Reversibility

scholarly journals Testing for Detailed Balance (Microscopic Reversibility) in IonChannel Gating

2001 ◽  
Vol 80 (6) ◽  
pp. 3025-3026 ◽  
Author(s):  
Brad S. Rothberg ◽  
Karl L. Magleby
Keyword(s):  
Detailed Balance ◽  
Microscopic Reversibility

Dielectronic Recombination in the Average-Atom Model

1988 ◽  
Vol 102 ◽  
pp. 215
Author(s):  
R.M. More ◽  
G.B. Zimmerman ◽  
Z. Zinamon
Keyword(s):  
Detailed Balance ◽  
Systematic Errors ◽  
Dielectronic Recombination ◽  
Rate Equations ◽  
Strong Correlations ◽  
Dense Plasmas ◽  
Atom Model ◽  
New Feature ◽  
Average Atom Model ◽  
Attachment Process

Autoionization and dielectronic attachment are usually omitted from rate equations for the non–LTE average–atom model, causing systematic errors in predicted ionization states and electronic populations for atoms in hot dense plasmas produced by laser irradiation of solid targets. We formulate a method by which dielectronic recombination can be included in average–atom calculations without conflict with the principle of detailed balance. The essential new feature in this extended average atom model is a treatment of strong correlations of electron populations induced by the dielectronic attachment process.

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