Effects of variations in reaction coordinate eigenvalue on heavy‐atom kinetic isotope effects: Comparison of two methods for curving the potential barrier

Richard W. Kidd; Peter E. Yankwich

doi:10.1063/1.1681082

Effects of variations in reaction coordinate eigenvalue on heavy‐atom kinetic isotope effects: Comparison of two methods for curving the potential barrier

The Journal of Chemical Physics ◽

10.1063/1.1681082 ◽

1974 ◽

Vol 60 (2) ◽

pp. 610-619 ◽

Cited By ~ 2

Author(s):

Richard W. Kidd ◽

Peter E. Yankwich

Keyword(s):

Potential Barrier ◽

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Reaction Coordinate ◽

Kinetic Isotope

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Mechanisms of elimination reactions. 30. The contributions of tunneling and heavy-atom motion in the reaction coordinate to deuterium kinetic isotope effects in eliminations from 2-phenylethyl derivatives

Journal of the American Chemical Society ◽

10.1021/ja00519a021 ◽

1979 ◽

Vol 101 (25) ◽

pp. 7594-7599 ◽

Cited By ~ 8

Author(s):

Sheena B. Kaldor ◽

William H. Saunders

Keyword(s):

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Reaction Coordinate ◽

Kinetic Isotope ◽

Elimination Reactions ◽

Atom Motion

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ChemInform Abstract: MECHANISMS OF ELIMINATION REACTIONS. 30. THE CONTRIBUTIONS OF TUNNELING AND HEAVY-ATOM MOTION IN THE REACTION COORDINATE TO DEUTERIUM KINETIC ISOTOPE EFFECTS IN ELIMINATIONS FROM 2-PHENYLETHYL DERIVATIVES

Chemischer Informationsdienst ◽

10.1002/chin.198010083 ◽

1980 ◽

Vol 11 (10) ◽

Author(s):

S. B. KALDOR ◽

W. H. JUN. SAUNDERS

Keyword(s):

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Reaction Coordinate ◽

Kinetic Isotope ◽

Elimination Reactions ◽

Atom Motion

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Effects of variations in reaction coordinate eigenvalue on heavy‐atom kinetic isotope effects: Eigenvectors consisting of one and two nonzero elements

The Journal of Chemical Physics ◽

10.1063/1.1680391 ◽

1973 ◽

Vol 59 (5) ◽

pp. 2723-2737 ◽

Cited By ~ 3

Author(s):

Richard W. Kidd ◽

Peter E. Yankwich

Keyword(s):

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Reaction Coordinate ◽

Kinetic Isotope

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Theoretical Simulations of Heavy-Atom Kinetic Isotope Effects in Aliphatic Claisen Rearrangement

The Journal of Physical Chemistry A ◽

10.1021/acs.jpca.0c07784 ◽

2020 ◽

Vol 124 (51) ◽

pp. 10678-10686

Author(s):

Yuqing Xu ◽

Kin-Yiu Wong ◽

Meishan Wang ◽

Desheng Liu ◽

Wenkai Zhao ◽

...

Keyword(s):

Claisen Rearrangement ◽

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Kinetic Isotope ◽

Theoretical Simulations

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Measurement of heavy atom kinetic isotope effects by direct mass spectrometric analysis

Analytical Chemistry ◽

10.1021/ac50045a009 ◽

1979 ◽

Vol 51 (9) ◽

pp. 1375-1379 ◽

Cited By ~ 10

Author(s):

Steven. Rosenberg ◽

Jack F. Kirsch

Keyword(s):

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Mass Spectrometric ◽

Mass Spectrometric Analysis ◽

Spectrometric Analysis ◽

Kinetic Isotope

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ChemInform Abstract: BENZIDINE REARRANGEMENTS. 18. MECHANISM OF THE ACID-CATALYZED DISPROPORTIONATION OF 4,4′-DIIODOHYDRAZOBENZENE. APPLICATION OF HEAVY-ATOM KINETIC ISOTOPE EFFECTS

Chemischer Informationsdienst ◽

10.1002/chin.198332088 ◽

1983 ◽

Vol 14 (32) ◽

Author(s):

H. J. SHINE ◽

J. HABDAS ◽

H. KWART ◽

M. BRECHBIEL ◽

A. G. HORGAN ◽

...

Keyword(s):

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Kinetic Isotope ◽

Acid Catalyzed

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Medium effects on heavy-atom kinetic isotope effects. I. Cell model without internal external coordinate interaction

Journal of the American Chemical Society ◽

10.1021/ja00796a008 ◽

1973 ◽

Vol 95 (15) ◽

pp. 4811-4815 ◽

Cited By ~ 5

Author(s):

Joseph H. Keller ◽

Peter E. Yankwich

Keyword(s):

Cell Model ◽

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Medium Effects ◽

Kinetic Isotope

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Heavy-Atom Kinetic Isotope Effects: Primary Interest or Zero Point?

Journal of the American Chemical Society ◽

10.1021/jacs.1c07351 ◽

2021 ◽

Author(s):

Harvey J. A. Dale ◽

Andrew G. Leach ◽

Guy C. Lloyd-Jones

Keyword(s):

Isotope Effects ◽

Heavy Atom ◽

Zero Point ◽

Kinetic Isotope Effects ◽

Primary Interest ◽

Kinetic Isotope

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Heavy-Atom Kinetic Isotope Effects, Cocatalysts, and the Propagation Transition State for Polymerization of 1-Hexene Using therac-(C2H4(1-indenyl)2)ZrMe2Catalyst Precursor

Journal of the American Chemical Society ◽

10.1021/ja026608k ◽

2002 ◽

Vol 124 (41) ◽

pp. 12062-12063 ◽

Cited By ~ 29

Author(s):

Clark R. Landis ◽

Kimberly A. Rosaaen ◽

Jamal Uddin

Keyword(s):

Transition State ◽

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Kinetic Isotope

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ChemInform Abstract: MEDIUM EFFECTS ON HEAVY-ATOM KINETIC ISOTOPE EFFECTS PART 3, STRUCTURED MEDIUM MODEL APPLIED TO COMPLEX FORMATION VIA MASS POINT ATTACHMENT AND COUPLING

Chemischer Informationsdienst ◽

10.1002/chin.197425049 ◽

1974 ◽

Vol 5 (25) ◽

pp. no-no

Author(s):

JOSEPH H. KELLER ◽

PETER E. YANKWICH

Keyword(s):

Complex Formation ◽

Isotope Effects ◽

Heavy Atom ◽

Kinetic Isotope Effects ◽

Mass Point ◽

Medium Effects ◽

Kinetic Isotope ◽

Medium Model

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