Nitrogen-14 and sodium-23 nuclear magnetic resonance of sodium and potassium cyanide

1973 ◽  
Vol 58 (7) ◽  
pp. 3018 ◽  
Author(s):  
Donald E. O'Reilly
1973 ◽  
Vol 13 (8) ◽  
pp. 763-771 ◽  
Author(s):  
J.A. Magnuson ◽  
Nancy S. Magnuson ◽  
D.L. Hendrix ◽  
N. Higinbotham

1971 ◽  
Vol 49 (17) ◽  
pp. 2906-2909 ◽  
Author(s):  
J. A. Ripmeester ◽  
B. A. Dunell

Differential scanning calorimeter thermograms have been obtained for the alkali metal stearates from 25 to 200 °C. Four different samples of different thermal history were studied for each soap, and differences in temperature and relative enthalpy of transitions were found to depend on the various sample histories. For lithium stearate good correlation is found between DSC and nuclear magnetic resonance (n.m.r.) results. Rubidium and caesium stearates seem to be less sensitive to thermal history than the sodium and potassium salts.


Author(s):  
M.J. Hennessy ◽  
E. Kwok

Much progress in nuclear magnetic resonance microscope has been made in the last few years as a result of improved instrumentation and techniques being made available through basic research in magnetic resonance imaging (MRI) technologies for medicine. Nuclear magnetic resonance (NMR) was first observed in the hydrogen nucleus in water by Bloch, Purcell and Pound over 40 years ago. Today, in medicine, virtually all commercial MRI scans are made of water bound in tissue. This is also true for NMR microscopy, which has focussed mainly on biological applications. The reason water is the favored molecule for NMR is because water is,the most abundant molecule in biology. It is also the most NMR sensitive having the largest nuclear magnetic moment and having reasonable room temperature relaxation times (from 10 ms to 3 sec). The contrast seen in magnetic resonance images is due mostly to distribution of water relaxation times in sample which are extremely sensitive to the local environment.


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