scholarly journals Comment on continuity at the dissociation threshold in molecular absorption

1973 ◽  
Vol 58 (11) ◽  
pp. 5187-5188 ◽  
Author(s):  
A. C. Allison ◽  
William C. Stwalley
Keyword(s):  
Molecular Absorption ◽  
Dissociation Threshold

Continuity at the Dissociation Threshold in Molecular Absorption

1971 ◽  
Vol 55 (9) ◽  
pp. 4342-4344 ◽  
Author(s):  
A. C. Allison ◽  
A. Dalgarno
Keyword(s):  
Molecular Absorption ◽  
Dissociation Threshold

Polarimetric Observations of Red Variables: A Study of Gas and Particle Interactions

1979 ◽  
Vol 46 ◽  
pp. 386-408 ◽  
Author(s):  
G. V. Coyne ◽  
I. S. McLean
Keyword(s):  
Wavelength Dependence ◽  
Stellar Atmosphere ◽  
Molecular Absorption ◽  
Absorption Bands ◽  
Absorption And Emission ◽  
Mira Variables ◽  
Stellar Photosphere ◽  
Regular Variable ◽  
Red Supergiants ◽  
Balmer Lines

AbstractIn recent years the wavelength, dependence of the polarization in a number of Mira variables, semi-regular variables and red supergiants has been measured with resolutions between 0.3 and 300 A over the range 3300 to 11000 A. Variations are seen across molecular absorption bands, especially TiO bands, and across atomic absorption and emission lines, especially the Balmer lines. In most cases one can ignore or it is possible to eliminate the effects due to interstellar polarization, so that one can study the polarization mechanisms operating in the stellar atmosphere and environment. The stars Omicron Ceti. (Mira), V CVn (semi-regular variable) and Mu Cephei (M2 la), in addition to other stars similar to them, will be discussed in some detail.Models to explain the observed polarization consider that the continuum flux is polarized either by electron, molecular and/or grain scattering or by temperature variations and/or geometrical asymmetries over the stellar photosphere. This polarized radiation is affected by atomic and molecular absorption and emission processes at various geometric depths in the stellar atmosphere and envelope. High resolution spectropolarimetry promises, therefore, to be a power-rul tool for studying stratification effects in these stars.

Software system for numerical simulation of broadband laser gas analysis of the atmosphere

2018 ◽  
pp. 66-73 ◽  
Author(s):  
S. A. Sadovnikov
Keyword(s):  
Numerical Simulation ◽  
Laser Radiation ◽  
Gas Analysis ◽  
Modular System ◽  
Software System ◽  
Transmission Spectra ◽  
Molecular Absorption ◽  
Molecular Scattering ◽  
Atmospheric Transmission ◽  
Wide Range

Introduction: Successful monitoring of environmental parameters requires the development of flexible software complexes with evolvable calculation functionality. Purpose: Developing a modular system for numerical simulation of atmospheric laser gas analysis. Results: Based on differential absorption method, a software system has been developed which provides the calculation of molecular absorption cross-sections, molecular absorption coefficients, atmospheric transmission spectra, and lidar signals. Absorption line contours are calculated using the Voigt profile. The prior information sources are HITRAN spectroscopic databases and statistical models of the distribution of temperature, pressure and gas components in the atmosphere. For modeling lidar signals, software blocks of calculating the molecular scattering coefficient and aerosol absorption/scattering coefficients were developed. For testing the applicability of various laser sources in the problems of environmental monitoring of the atmosphere, a concentration reconstruction error calculation block was developed for the atmospheric gas components, ignoring the interfering absorption of laser radiation by foreign gases. To verify the correct functioning of the software, a program block was developed for comparing the results of the modeling of atmospheric absorption and transmission spectra by using the standard SPECTRA information system. The discrepancy between the calculation of the atmospheric transmission spectra obtained using the developed system as compared to the SPECTRA results is less than 1%. Thus, a set of the presented program blocks allows you to carry out complex modeling of remote atmospheric gas analysis. Practical relevance: The software complex allows you to rapidly assess the possibilities of using a wide range of laser radiation sources for the problems of remote gas analysis.

scholarly journals An Improved Methodology for Determination of Fluorine in Biological Samples Using High-Resolution Molecular Absorption Spectrometry via Gallium Fluorine Formation in a Graphite Furnace

2021 ◽  
Vol 11 (12) ◽  
pp. 5493
Author(s):  
Andrzej Gawor ◽  
Andrii Tupys ◽  
Anna Ruszczyńska ◽  
Ewa Bulska
Keyword(s):  
High Resolution ◽  
Limit Of Detection ◽  
Graphite Furnace ◽  
Absorption Spectrometry ◽  
Biological Tissues ◽  
Biologically Active ◽  
Molecular Absorption ◽  
Biological Origin ◽  
Molecular Absorption Spectrometry

Nowadays growing attention is paid to the control of fluorine content in samples of biological origin as it is present in the form of various biologically active organic compounds. Due to the chemically-rich matrix of biological tissues, the determination of fluorine becomes a very difficult task. Furthermore, a required complex sample preparation procedure makes the determination of the low contents of F by ion chromatography UV-Vis or ion-selective electrodes not possible. High-resolution continuum source graphite furnace molecular absorption spectrometry (HR-CS GF MAS) seems to be the best option for this purpose due to its high robustness to matrix interferences, especially in the presence of carefully selected modifiers. In this work the possibility of quantitative F determination in water and animal tissues was examined by measuring the molecular absorption of gallium monofluoride (GaF) at 211.248 nm with the use of a commercially available HR-CS GF MAS system. Experimental conditions for the sensitive and precise determination of fluorine were optimized, including the time/temperature program as well as addition of gallium and modifier mixture in combined mode. Under these conditions the fluoride present in the sample was stabilized up to 600 °C, and the optimum vaporization temperature for GaF was 1540 °C. Palladium and zirconium deposited onto the graphite surface served as solid modifiers; sodium acetate and ruthenium modifiers were added directly to the sample. The limit of detection and the characteristic mass of the method were 0.43 μg/L and 8.7 pg, respectively. The proposed procedure was validated by the use of certified reference materials (CRMs) of lake water and animal tissue; the acceptable recovery was obtained, proving that it can be applied for samples with a similar matrix.

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