Gas Phase Pulse Radiolysis of Hydrocarbon Mixtures; Determination of the Charge Recombination Rate Coefficient and Absolute Rate Constants of Ion‐Molecule Reactions of thet‐Butyl Ion through a Competitive Kinetic Method

1972 ◽  
Vol 57 (5) ◽  
pp. 2080-2086 ◽  
Author(s):  
S. G. Lias ◽  
R. E. Rebbert ◽  
P. Ausloos
Keyword(s):  
Gas Phase ◽  
Recombination Rate ◽  
Pulse Radiolysis ◽  
Rate Coefficient ◽  
Kinetic Method ◽  
Absolute Rate ◽  
Hydrocarbon Mixtures ◽  
Ion Molecule Reactions ◽  
Recombination Rate Coefficient

scholarly journals Determination of the $\ion{Ni}{xviii}$ plasma recombination rate coefficient

2003 ◽  
Vol 409 (2) ◽  
pp. 781-786 ◽  
Author(s):  
M. Fogle ◽  
N. R. Badnell ◽  
N. Eklöw ◽  
T. Mohamed ◽  
R. Schuch
Keyword(s):  
Recombination Rate ◽  
Rate Coefficient ◽  
Recombination Rate Coefficient

Determination of the N2+recombination rate coefficient in the ionosphere

1977 ◽  
Vol 4 (10) ◽  
pp. 431-433 ◽  
Author(s):  
N. Orsini ◽  
D. G. Torr ◽  
H. C. Brinton ◽  
L. H. Brace ◽  
W. B. Hanson ◽  
...  
Keyword(s):  
Recombination Rate ◽  
Rate Coefficient ◽  
Recombination Rate Coefficient

scholarly journals Chemical Reactions in Astrochemistry

1992 ◽  
Vol 150 ◽  
pp. 7-12
Author(s):  
B. R. Rowe
Keyword(s):  
Low Temperature ◽  
Gas Phase ◽  
Chemical Reactions ◽  
Rate Coefficient ◽  
Branching Ratio ◽  
Dissociative Recombination ◽  
Experimental Techniques ◽  
Ion Molecule Reactions

This paper is devoted to chemistry in the gas phase dealing firstly with ion-molecule reactions at extremely low temperature. The experimental techniques that have been used in this field are shortly presented and the reactions that have been studied using the CRESU(S) method reviewed. In the second part, the most recent measurements concerning dissociative recombination are discussed, including studies of branching ratio and new determination of the rate coefficient for H+3 ions.

scholarly journals Calculation of the ion–ion recombination rate coefficient via a hybrid continuum-molecular dynamics approach

2020 ◽  
Vol 152 (9) ◽  
pp. 094306 ◽  
Author(s):  
Tomoya Tamadate ◽  
Hidenori Higashi ◽  
Takafumi Seto ◽  
Christopher J. Hogan
Keyword(s):  
Molecular Dynamics ◽  
Recombination Rate ◽  
Rate Coefficient ◽  
Ion Recombination ◽  
Recombination Rate Coefficient

Further measurements of the H+3(v=0,1,2) dissociative recombination rate coefficient

1992 ◽  
Vol 97 (2) ◽  
pp. 1028-1037 ◽  
Author(s):  
A. Canosa ◽  
J. C. Gomet ◽  
B. R. Rowe ◽  
J. B. A. Mitchell ◽  
J. L. Queffelec
Keyword(s):  
Recombination Rate ◽  
Rate Coefficient ◽  
Dissociative Recombination ◽  
Recombination Rate Coefficient

The fluoroformate ion, FCO2−. An ion cyclotron resonance study of the gas phase Lewis acidity of carbon dioxide and related isoelectronic species

1978 ◽  
Vol 56 (8) ◽  
pp. 1069-1074 ◽  
Author(s):  
Terrance Brian McMahon ◽  
Colleen Joan Northcott
Keyword(s):  
Carbon Dioxide ◽  
Gas Phase ◽  
Lewis Acidity ◽  
Ion Cyclotron Resonance ◽  
Dissociation Energies ◽  
Ion Molecule Reactions ◽  
Gas Phase Acidity ◽  
Gas Phase Ion ◽  
Carbonyl Fluoride

The gas phase ion molecule reactions of a number of potential fluoride donors with carbon dioxide and carbonyl fluoride have been studied. By determination of preferential directions of fluoride transfer the fluoride affinities of carbon dioxide and carbonyl fluoride have been bracketed and found to be 33 ± 3 kcal/mol and 35 + 3 kcal/mol respectively. In addition, from gas phase acidity studies of acetyl fluoride and 2-fluoropropene the fluoride affinities of ketene and allene have been calculated to be 38 ± 2 kcal/mol and 15 ± 2 kcal/mol respectively. The order of fluoride affinities (Lewis acidities) of carbon dioxide, ketene, and allene have been examined and explained in terms of the electron affinities of the F—C(A)(B) species (A,B=O,CH2) and the C—F bond dissociation energies. These quantities have been estimated and the latter interpreted on the basis of the π bond energies of the three compounds.

Sign in / Sign up

Export Citation Format

Share Document