Absorption Spectrum and Reaction Kinetics of the HO2Radical in the Gas Phase

1972 ◽  
Vol 56 (9) ◽  
pp. 4426-4432 ◽  
Author(s):  
C. J. Hochanadel ◽  
J. A. Ghormley ◽  
Paul J. Ogren
Keyword(s):  
Absorption Spectrum ◽  
Reaction Kinetics ◽  
Gas Phase ◽  
Kinetics Of

Modulation spectroscopy. Kinetics for the self-reactions of some α-aminoalkyl radicals in solution

1982 ◽  
Vol 60 (3) ◽  
pp. 274-278 ◽  
Author(s):  
Paul R. Marriott ◽  
Arlindo L. Castelhano ◽  
David Griller
Keyword(s):  
Absorption Spectrum ◽  
Reaction Kinetics ◽  
Unpaired Electron ◽  
Rate Constants ◽  
Lone Pair ◽  
The Self ◽  
Modulation Spectroscopy ◽  
Alkyl Radicals ◽  
Diffusion Controlled ◽  
Kinetics Of

The optical spectra and reaction kinetics of some a-aminoalkyl radicals, RĊHN(CH2R)2; R≡H, Me, Ph, were measured in solution using the technique of modulation spectroscopy. These radicals undergo diffusion controlled self-reaction with rate constants [Formula: see text]. When R≡Ph, the absorption spectrum has a well defined maximum at 346 nm; ε = 3390 M−1 cm−1, while the spectra when R≡H or Me were less intense [Formula: see text] and tailed into the visible. These spectra are substantially red-shifted when compared with those of simple alkyl radicals, an effect which is thought to be due to the interaction between the unpaired electron and the lone pair of electrons on nitrogen.

UV absorption spectrum of CH3OCH2 radicals and kinetics of the reaction of CH3OCH2O2 radicals with NO and NO2 in the gas phase

1995 ◽  
Vol 240 (1-3) ◽  
pp. 53-56 ◽  
Author(s):  
Sarka Langer ◽  
Evert Ljungström ◽  
Thomas Ellermann ◽  
Ole J. Nielsen ◽  
Jens Sehested
Keyword(s):  
Absorption Spectrum ◽  
Gas Phase ◽  
Uv Absorption ◽  
Kinetics Of ◽  
Uv Absorption Spectrum

Reaction kinetics of nitrogen dioxide with methanol in the gas phase

1985 ◽  
Vol 19 (3) ◽  
pp. 262-264 ◽  
Author(s):  
Seiichiro. Koda ◽  
Kota. Yoshikawa ◽  
Jun. Okada ◽  
Kazuo. Akita
Keyword(s):  
Nitrogen Dioxide ◽  
Reaction Kinetics ◽  
Gas Phase ◽  
Kinetics Of
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