Ultrasonic Investigation of Acetic Acid Hydrogen Bond Formation. II Acetic Acid–Water Solutions

1971 ◽  
Vol 55 (4) ◽  
pp. 1971-1978 ◽  
Author(s):  
Robert D. Corsaro ◽  
Gordon Atkinson
Keyword(s):  
Hydrogen Bond ◽  
Acetic Acid ◽  
Bond Formation ◽  
Acid Water ◽  
Hydrogen Bond Formation ◽  
Water Solutions ◽  
Acetic Acid Water ◽  
Ultrasonic Investigation

Temperature Dependence of Hydrogen-Bond Dynamics in Acetic Acid−Water Solutions

2010 ◽  
Vol 114 (32) ◽  
pp. 10628-10633 ◽  
Author(s):  
Francesco D’Amico ◽  
Filippo Bencivenga ◽  
Alessandro Gessini ◽  
Claudio Masciovecchio
Keyword(s):  
Hydrogen Bond ◽  
Acetic Acid ◽  
Temperature Dependence ◽  
Acid Water ◽  
Water Solutions ◽  
Acetic Acid Water ◽  
Hydrogen Bond Dynamics

Stability of a Water-Stable Lithium Metal Anode for a Lithium–Air Battery with Acetic Acid–Water Solutions

2010 ◽  
Vol 157 (2) ◽  
pp. A214 ◽  
Author(s):  
Tao Zhang ◽  
Nobuyuki Imanishi ◽  
Yuta Shimonishi ◽  
Atsushi Hirano ◽  
Jian Xie ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Acid Water ◽  
Lithium Metal ◽  
Water Solutions ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Acetic Acid Water ◽  
Air Battery

Vapochromism induced by intermolecular electron transfer coupled with hydrogen-bond formation in zinc dithiolene complex

2020 ◽  
Vol 8 (42) ◽  
pp. 14939-14947
Author(s):  
So Yokomori ◽  
Shun Dekura ◽  
Tomoko Fujino ◽  
Mitsuaki Kawamura ◽  
Taisuke Ozaki ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Electron Transfer ◽  
Bond Formation ◽  
Intermolecular Electron Transfer ◽  
Hydrogen Bond Formation ◽  
Complex Crystal

A novel vapochromic mechanism by intermolecular electron transfer coupled with hydrogen-bond formation was realized in a zinc dithiolene complex crystal.

Diverse mechanisms of carbon-hydrogen bond formation through binuclear reductive elimination reactions

1982 ◽  
Vol 104 (2) ◽  
pp. 619-621 ◽  
Author(s):  
Mario J. Nappa ◽  
Roberto Santi ◽  
Steven P. Diefenbach ◽  
Jack Halpern
Keyword(s):  
Hydrogen Bond ◽  
Bond Formation ◽  
Reductive Elimination ◽  
Hydrogen Bond Formation ◽  
Elimination Reactions

Theoretical analysis of the (HNO)2, (HNO···HNS), and (HNS)2 dimers — A case of red and blue shifts of N–H stretching frequency

2010 ◽  
Vol 88 (8) ◽  
pp. 849-857 ◽  
Author(s):  
Nguyen Tien Trung ◽  
Tran Thanh Hue ◽  
Minh Tho Nguyen
Keyword(s):  
Hydrogen Bond ◽  
Quantum Chemical ◽  
Bond Formation ◽  
Blue Shift ◽  
Proton Donor ◽  
Basis Sets ◽  
Coupled Cluster ◽  
Hydrogen Bond Formation ◽  
Length Contraction ◽  
Moller Plesset

The hydrogen-bonded interactions in the simple (HNZ)2 dimers, with Z = O and S, were investigated using quantum chemical calculations with the second-order Møller–Plesset perturbation (MP2), coupled-cluster with single, double (CCSD), and triple excitations (CCSD(T)) methods in conjunction with the 6-311++G(2d,2p), aug-cc-pVDZ, and aug-cc-pVTZ basis sets. Six-membered cyclic structures were found to be stable complexes for the dimers (HNO)2, (HNS)2, and (HNO–HNS). The pair (HNS)2 has the largest complexation energy (–11 kJ/mol), and (HNO)2 the smallest one (–9 kJ/mol). A bond length contraction and a frequency blue shift of the N–H bond simultaneously occur upon hydrogen bond formation of the N–H···S type, which has rarely been observed before. The stronger the intramolecular hyperconjugation and the lower the polarization of the X–H bond involved as proton donor in the hydrogen bond, the more predominant is the formation of a blue-shifting hydrogen bond.

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