Pulse Radiolysis Studies. XX. Kinetics of Some Addition Reactions of Gaseous Hydrogen Atoms by Fast Lyman‐α Absorption Spectrophotometry

1971 ◽  
Vol 54 (8) ◽  
pp. 3422-3428 ◽  
Author(s):  
T. Hikida ◽  
J. A. Eyre ◽  
Leon M. Dorfman
Keyword(s):  
Pulse Radiolysis ◽  
Gaseous Hydrogen ◽  
Addition Reactions ◽  
Hydrogen Atoms ◽  
Absorption Spectrophotometry ◽  
Kinetics Of

Reaction kinetics of gaseous hydrogen atoms with graphite

1969 ◽  
Vol 73 (5) ◽  
pp. 1348-1351 ◽  
Author(s):  
Bernard J. Wood ◽  
Henry Wise
Keyword(s):  
Reaction Kinetics ◽  
Gaseous Hydrogen ◽  
Hydrogen Atoms ◽  
Kinetics Of

Radical-induced redox and addition reactions with C60studied by pulse radiolysis

1993 ◽  
pp. 84-86 ◽  
Author(s):  
Dirk M. Guldi ◽  
Hartmut Hungerbühler ◽  
Eberhard Janata ◽  
Klaus-Dieter Asmus
Keyword(s):  
Pulse Radiolysis ◽  
Addition Reactions

Reactions of hydrogen atoms with hexafluoroacetone

1978 ◽  
Vol 56 (20) ◽  
pp. 2638-2645 ◽  
Author(s):  
D. W. Grattan ◽  
K. O. Kutschke
Keyword(s):  
Rate Constant ◽  
Cross Sections ◽  
The Other ◽  
Hydrogen Atoms ◽  
Kinetics Of

Attempts were made to study the kinetics of the reaction of atomic H with (CF3)2CO vapour (HFA). Atomic H was generated from H2 by mercury photosensitization in the presence of C2H4 and HFA but the system was complicated by the loss of C2H5 radicals by addition to HFA and the kinetic results were intractable. When atomic H was generated from C3H8, the kinetics again were obscured by some unidentified reaction(s) which became more important at higher [HFA]/[C3H8]. An estimate of the rate constant for the addition of H to HFA obtained at low [HFA]/[C3H8] yielded k9 = 8.5 × 105 l mol−1 s−1. Trifluoroacetaldehyde was identified with some reliability but many of the other heavier products formed in the H2 + HFA reaction could not be identified. Quenching cross-sections were determined for C2H4, C3H8, C4H10, and HFA relative to that for N2O.

Kinetics of H abstraction and addition reactions of 2,4,4-trimethyl-1-pentene by OH radical

Fuel ◽  
2017 ◽  
Vol 210 ◽  
pp. 646-658 ◽  
Author(s):  
Geyuan Yin ◽  
Erjiang Hu ◽  
Feiyu Yang ◽  
Jinfeng Ku ◽  
Zuohua Huang
Keyword(s):  
Addition Reactions ◽  
Oh Radical ◽  
Kinetics Of
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