Effects of High Rotational Quantum Numbers on Rydberg–Klein–Rees Franck–Condon Factors: The Nitric Oxide (NO) Beta Band System

1970 ◽  
Vol 53 (8) ◽  
pp. 3147-3152 ◽  
Author(s):  
John I. Generosa ◽  
Richard A. Harris
Keyword(s):  
Nitric Oxide ◽  
Band System ◽  
Beta Band ◽  
Quantum Numbers ◽  
Condon Factors ◽  
Franck Condon

A theoretical study of the B′2Σ+–X2Σ+ band system in MgH and MgD

1979 ◽  
Vol 57 (8) ◽  
pp. 1178-1184 ◽  
Author(s):  
M. L. Sink ◽  
A. D. Bandrauk
Keyword(s):  
Dipole Moment ◽  
Theoretical Study ◽  
Transition Probabilities ◽  
Band System ◽  
Dipole Moments ◽  
Electronic States ◽  
Oscillator Strengths ◽  
Moment Functions ◽  
Condon Factors ◽  
Franck Condon

Ab initio Cl calculations of the transition moment for the B′2Σ+–X2Σ+ transition in MgH are reported. Theoretical values for the Franck–Condon factors, band strengths, band oscillator strengths, and transition probabilities have been computed for MgH and MgD. An analysis of our results for this system predicts many bands to be observable which have not yet been identified. Dipole moment functions and vibrationally averaged dipole moments are given for the X2Σ+, A2Π, and B′2Σ+ electronic states.

FRANCK–CONDON FACTORS AND r-CENTROIDS TO HIGH VIBRATIONAL QUANTUM NUMBERS FOR THREE BAND SYSTEMS OF CO+ AND ABSOLUTE BAND STRENGTHS FOR THE COMET-TAIL SYSTEM

1962 ◽  
Vol 40 (12) ◽  
pp. 1772-1783 ◽  
Author(s):  
R. W. Nicholls
Keyword(s):  
Comet Tail ◽  
Condon Factor ◽  
Quantum Numbers ◽  
Condon Factors ◽  
Franck Condon ◽  
Morse Potentials

Franck–Condon factor and r-centroid arrays computed to high vibrational quantum numbers for Morse potentials are displayed for the CO+ comet-tail (A2Πi–X2Σ+), first negative (B2Σ+–X2Σ+), and Baldet–Johnson (B2Σ+–A2Πi) band systems. Estimates of band strengths are made for CO+ comet-tail bands.

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