Paramagnetic Anisotropy, Low Temperature Magnetization, and Electronic Structure of Iron(II) Phthalocyanine

1970 ◽  
Vol 53 (5) ◽  
pp. 1643-1648 ◽  
Author(s):  
C. G. Barraclough ◽  
R. L. Martin ◽  
S. Mitra ◽  
R. C. Sherwood
1978 ◽  
Vol 39 (C6) ◽  
pp. C6-416-C6-417
Author(s):  
B. M. Klein ◽  
L. L. Boyer ◽  
D. A. Papaconstantopoulos

2017 ◽  
Vol 4 (9) ◽  
pp. 094001
Author(s):  
G Krishnamurthy Grandhi ◽  
Renu Tomar ◽  
Ranjani Viswanatha

Author(s):  
Nikolay G. Maksimov ◽  
Victor V. Verpekin ◽  
Dmitry V. Zimonin ◽  
Galina V. Burmakina ◽  
Oleg S. Chudin ◽  
...  

The chemical oxidation of the cluster CpReFePt(μ3-C=CHPh)(CO)5(dppe) (Cp = η5-C5H5, dppe = η2- Ph2P(CH2)2PPh2) resulted in a radical cation [CpReFePt(μ3-C=CHPh)(CO)5(dppe)]+• that is sufficiently stable only at low temperature. An electronic structure of the radical cation was studied by EPR and following parameters were obtained by comparison of the experimental and model spectrum: gx = 2.070 gy = 2.0295 gz = 1.997; Ax(31P) = 17 Ay(31P) = 49 Az(31P) = 35 (Gs);Ax(195Pt) = 62 Ay(195Pt) = 45 Az(195Pt) = 105 (Gs). An unpaired electron is seen to be mainly concentrated on the iron atom (85-90%) and partially on the platinum atom (10-15%). Further transformation of the radical cation led to the formation of the binuclear complex Cp(CO)2RePt(μ-C=CHPh)(dppe) and the Fe-carbonyl fragment


1984 ◽  
Vol 57 (5-6) ◽  
pp. 629-649 ◽  
Author(s):  
M. Dacorogna ◽  
T. Jarlborg ◽  
A. Junod ◽  
M. Pelizzone ◽  
M. Peter

RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 52048-52057 ◽  
Author(s):  
J.-B. Vaney ◽  
J.-C. Crivello ◽  
C. Morin ◽  
G. Delaizir ◽  
J. Carreaud ◽  
...  

The first-order lattice distortion undergone by β-As2Te3 around 200 K results in a cycling effect on its transport properties.


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