Shock‐Tube Study of the Acetylene–Oxygen Reaction. I. CH(A 2Δ→X 2π) Chemiluminescence and CO Production during the Induction Period

1970 ◽  
Vol 52 (8) ◽  
pp. 4122-4132 ◽  
Author(s):  
David Gutman ◽  
Shimpei Matsuda
1972 ◽  
Vol 57 (12) ◽  
pp. 5277-5285 ◽  
Author(s):  
Shimpei Matsuda ◽  
Irene R. Slagle ◽  
Dennis J. Fife ◽  
John R. Marquart ◽  
David Gutman

1970 ◽  
Vol 15 (2) ◽  
pp. 125-132 ◽  
Author(s):  
Casimir J. Jachimowski ◽  
William M. Houghton

1971 ◽  
Vol 49 (23) ◽  
pp. 3904-3907
Author(s):  
David Gutman ◽  
Shimpei Matsuda

The Cr* (a7S–y7P) chemiluminescence at 360 nm during the induction period of the C2H2–O2 reaction was studied behind reflected shock waves. When the reaction gas mixture containing 10 p.p.m. Cr(CO)6, 0.5% C2H2, 1.0% O2, and 98.5% Ar was shock heated to 1650 °K, the emission intensity of Cr* grew exponentially with a growth constant equal to the chain branching constant. This observation indicates that reaction(s) leading to Cr* chemiluminescence involve only one chain carrier during the induction period of the C2H2–O2 reaction. The mechanism of the chemical excitation of Cr is discussed.


1967 ◽  
Vol 11 (1) ◽  
pp. 845-852 ◽  
Author(s):  
Tetsu Takeyama ◽  
Hajime Miyama

1965 ◽  
Vol 10 (1) ◽  
pp. 295-302 ◽  
Author(s):  
T. Asaba ◽  
W.C. Gardiner ◽  
R.F. Stubbeman

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