Partial Molal Heat Capacity at Infinite Dilution of Amino Acids in H2O and D2O Solutions at 25°

1970 ◽  
Vol 52 (11) ◽  
pp. 5966-5967 ◽  
Author(s):  
Gordon C. Kresheck
2017 ◽  
Vol 5 (10) ◽  
pp. 160-167
Author(s):  
Yasmin Akhtar

Densities, ultrasonic velocities and viscosities of L- Valine and L- Phenylalanine in aqueous sodium bromide (0.00, 0.025 and 0.05) m solutions have been determined experimentally at 308 and 313 K. The results obtained from density ultrasonic velocity and viscosity measurement have been used to calculate the apparent molal volume, фv, apparent molal, adiabatic compressibility ф Ks, partial molal volume ф0v at infinite dilution, partial molal adiabatic compressibility ф0Ks at infinite dilution, transfer volume ∆ф(tr), experimental slopes Sv and SKs,Falkenhagen coefficient A and  Jones-Dole B coefficient. The results are discussed in terms of the dehydration effect of the sodium bromide upon the amino acids and weak solute- solute and strong solute- solvent interactions. The properties of these amino acids in water and water + sodium bromide solution systems are discussed in terms of the charge, size and hydrogen bonding effect.


1975 ◽  
Vol 53 (23) ◽  
pp. 3634-3636 ◽  
Author(s):  
Carmel Jolicoeur ◽  
Patrick Picker ◽  
Gérald Perron

The direct specific heat measurement on aqueous benzene solutions by flow microcalorimetry have been repeated to elucidate discrepancies among earlier results. Through extensive variations of experimental conditions, the origin of difficulties encountered previously has been investigated and a simple procedure has been devised to circumvent problems inherent to this particular type of measurements.


1979 ◽  
Vol 8 (10) ◽  
pp. 717-727 ◽  
Author(s):  
Ernest E. Bernarducci ◽  
Lester R. Morss ◽  
Andrew R. Miksztal

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