Theory of Phase Transitions in Solid Methanes. II. Nuclear Spin Species A and T of Light Methane

1968 ◽  
Vol 48 (7) ◽  
pp. 3199-3216 ◽  
Author(s):  
Tsunenobu Yamamoto ◽  
Yosuke Kataoka
1982 ◽  
Vol 43 (7) ◽  
pp. 1049-1058 ◽  
Author(s):  
M. Goldman ◽  
J.F. Jacquinot

1990 ◽  
Vol 165-166 ◽  
pp. 783-784 ◽  
Author(s):  
A.J. Annila ◽  
K.N. Clausen ◽  
A.S. Oja ◽  
K. Siemensmeyer ◽  
M. Steiner ◽  
...  

1968 ◽  
Vol 48 (7) ◽  
pp. 2959-2965 ◽  
Author(s):  
H. P. Hopkins ◽  
R. F. Curl ◽  
Kenneth S. Pitzer

1974 ◽  
Vol 52 (5) ◽  
pp. 387-395 ◽  
Author(s):  
B. C. Sanctuary

For symmetric top molecules the role of nuclear spin symmetry is included in the derivation of the nuclear magnetic relaxation rate. It is assumed that this is dominated by a spin-rotation mechanism. Of the three nuclear spin species which exist for ZX3Y' symmetric tops, it is found that the "zero frequency" K = −1 to +1 term results in two of the species relaxing with a different rate from the third. The difference, which allows a direct NMR evaluation of the relative values of [Formula: see text] and [Formula: see text], is enhanced at low temperatures.


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