Barrier Studies in the Halopropenes. III. Microwave Spectra, Molecular Structure, Quadrupole Coupling Constants, Orientation of the Field Gradient Tensor, and Barrier to Internal Rotation in cis‐1‐Chloro‐2‐fluoropropene

1968 ◽  
Vol 48 (5) ◽  
pp. 1890-1897 ◽  
Author(s):  
R. G. Stone ◽  
S. L. Srivastava ◽  
W. H. Flygare
1976 ◽  
Vol 31 (7) ◽  
pp. 840-846
Author(s):  
F. Scappini ◽  
H. Dreizler

Abstract The microwave spectra of acetyl cyanide, CH3COCN, in the ground and in the two lowest excited states have been investigated. The rotational constants and the quadrupole coupling constants have been evaluated for all these states. The internal rotation parameters have been refined with respect to previous works. Evidence for a rotation-torsion -vibration interaction has been found in the spectra of the excited states.


1989 ◽  
Vol 44 (12) ◽  
pp. 1196-1200 ◽  
Author(s):  
N. Heineking ◽  
H. Dreizler ◽  
K. Endo ◽  
Y. Kamura

Abstract The rotational spectra of pyridine-N-oxide and x-picoline-N-oxide ( = 2-methvlpyridine-N-oxide) have been observed by means of pulsed microwave spectroscopy. For both molecules, the 14N quadrupole coupling constants have been obtained. For α-picoline-N-oxide. in addition the parameters of the internal rotation motion and the centrifugal distortion constants have been determined.


1971 ◽  
Vol 8 (1-2) ◽  
pp. 225-233 ◽  
Author(s):  
Lise Nygaard ◽  
Erik Asmussen ◽  
Jens H. Høg ◽  
R.C. Maheshwari ◽  
C.H. Nielsen ◽  
...  

1969 ◽  
Vol 3 (6) ◽  
pp. 491-506 ◽  
Author(s):  
Use Nygaard ◽  
J.Tormod Nielsen ◽  
Jørgen Kirchheiner ◽  
Gudrun Maltesen ◽  
J. Rastrup-Andersen ◽  
...  

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