scholarly journals High resolution measurements of kinetic energy release distributions of neon, argon, and krypton cluster ions using a three sector field mass spectrometer

2004 ◽  
Vol 120 (6) ◽  
pp. 2686-2692 ◽  
Author(s):  
K. Głuch ◽  
S. Matt-Leubner ◽  
L. Michalak ◽  
O. Echt ◽  
A. Stamatovic ◽  
...  
Keyword(s):  
High Resolution ◽  
Kinetic Energy ◽  
Energy Release ◽  
Mass Spectrometer ◽  
Kinetic Energy Release ◽  
Cluster Ions ◽  
Field Mass

scholarly journals High-resolution kinetic energy release distributions and dissociation energies for fullerene ions Cn+, 42⩽n⩽90

2004 ◽  
Vol 121 (5) ◽  
pp. 2137-2143 ◽  
Author(s):  
K. Głuch ◽  
S. Matt-Leubner ◽  
O. Echt ◽  
B. Concina ◽  
P. Scheier ◽  
...  
Keyword(s):  
High Resolution ◽  
Kinetic Energy ◽  
Energy Release ◽  
Kinetic Energy Release ◽  
Dissociation Energies

Peter J Derrick and the Grand Scale ‘Magnificent Mass Machine’ mass spectrometer at Warwick

2017 ◽  
Vol 23 (6) ◽  
pp. 319-326 ◽  
Author(s):  
AW Colburn ◽  
Peter J Derrick ◽  
Richard D Bowen
Keyword(s):  
Kinetic Energy ◽  
Energy Release ◽  
Gas Phase ◽  
Mass Spectrometer ◽  
Methyl Ether ◽  
Kinetic Energy Release ◽  
Neutral Complex ◽  
Ethyl Radical ◽  
Unpublished Work ◽  
Distonic Ions

The value of the Grand Scale ‘Magnificent Mass Machine’ mass spectrometer in investigating the reactivity of ions in the gas phase is illustrated by a brief analysis of previously unpublished work on metastable ionised n-pentyl methyl ether, which loses predominantly methanol and an ethyl radical, with very minor contributions for elimination of ethane and water. Expulsion of an ethyl radical is interpreted in terms of isomerisation to ionised 3-pentyl methyl ether, via distonic ions and, possibly, an ion-neutral complex comprising ionised ethylcyclopropane and methanol. This explanation is consistent with the closely similar behaviour of the labelled analogues, C3H7CH2CD2OCH3+. and C3H7CD2CH2OCH3+., and is supported by the greater kinetic energy release associated with loss of ethane from ionised n-propyl methyl ether compared to that starting from directly generated ionised 3-pentyl methyl ether.

scholarly journals Photodissociation Dynamics of Arn+ Cluster Ions

1994 ◽  
Vol 14 (1-3) ◽  
pp. 15-29 ◽  
Author(s):  
Takashi Nagata
Keyword(s):  
Kinetic Energy ◽  
Energy Release ◽  
Simulation Analysis ◽  
Kinetic Energy Release ◽  
Cluster Ions ◽  
Angular Distributions ◽  
High Kinetic Energy ◽  
Spectral Profiles ◽  
Direct Dissociation ◽  
Energy And Angular Distributions

The time-of-flight (TOF) spectra of Ar+ and Ar fragments produced in the photodissociation of Arn+ (3 ≦ n ≧ 24) were measured at wavelength around 540 nm. The kinetic-energy and angular distributions of the neutral photofragments were obtained for n = 3, 9 and 24 by a simulation analysis of the measured TOF spectral profiles. The overall aspect of the photodissociation process of Arn+ is deduced from these distributions within the context of trimer ion core model; a linear Ar3+ core is solvated by neutral Ar atoms. For Arn+ with 4 ≦ n ≲ 14, direct dissociation of the Ar3+ chromophoric core gives rise to Ar+ and/or Ar fragments with a high kinetic energy release. For the larger Arn+ (n ≳ 14), the production of high-kinetic-energy fragments is suppressed; “evaporation” of the solvent Ar atoms is instead the dominant channel of photofragmentation.

Decay reactions of rare gas cluster ions: Kinetic energy release distributions and binding energies

2001 ◽  
Vol 16 (1) ◽  
pp. 69-72 ◽  
Author(s):  
R. Parajuli ◽  
S. Matt ◽  
O. Echt ◽  
A. Stamatovic ◽  
P. Scheier ◽  
...  
Keyword(s):  
Kinetic Energy ◽  
Energy Release ◽  
Kinetic Energy Release ◽  
Binding Energies ◽  
Cluster Ions ◽  
Rare Gas
Sign in / Sign up

Export Citation Format

Share Document