scholarly journals Reactive vibrational excitation spectroscopy of formic acid in solid argon: Quantum yield for infrared inducedtrans→cisisomerization and solid state effects on the vibrational spectrum

2003 ◽  
Vol 119 (22) ◽  
pp. 11765-11772 ◽  
Author(s):  
E. M. S. Maçôas ◽  
L. Khriachtchev ◽  
M. Pettersson ◽  
J. Juselius ◽  
R. Fausto ◽  
...  
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
Vibrational Spectrum ◽  
Formic Acid ◽  
Vibrational Excitation ◽  
Solid Argon

scholarly journals Zn(II) Heteroleptic Halide Complexes with 2-Halopyridines: Features of Halogen Bonding in Solid State

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3393
Author(s):  
Mikhail A. Vershinin ◽  
Marianna I. Rakhmanova ◽  
Alexander S. Novikov ◽  
Maxim N. Sokolov ◽  
Sergey A. Adonin
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
Crystal Packing ◽  
Halogen Bonding ◽  
Molecular Complexes ◽  
Substituted Pyridines ◽  
Halide Complexes

Reactions between Zn(II) dihalides and 2-halogen-substituted pyridines 2-XPy result in a series of heteroleptic molecular complexes [(2-XPy)2ZnY2] (Y = Cl, X = Cl (1), Br (2), I (3); Y = Br, X = Cl (4), Br (5), I (6), Y = I, X = Cl (7), Br (8), and I (9)). Moreover, 1–7 are isostructural (triclinic), while 8 and 9 are monoclinic. In all cases, halogen bonding plays an important role in formation of crystal packing. Moreover, 1–9 demonstrate luminescence in asolid state; for the best emitting complexes, quantum yield (QY) exceeds 21%.

scholarly journals Conformational Isomerization of Formic Acid by Vibrational Excitation at Energies below the Torsional Barrier

2003 ◽  
Vol 125 (14) ◽  
pp. 4058-4059 ◽  
Author(s):  
Mika Pettersson ◽  
Ermelinda M. S. Maçôas ◽  
Leonid Khriachtchev ◽  
Rui Fausto ◽  
Markku Räsänen
Keyword(s):  
Formic Acid ◽  
Vibrational Excitation ◽  
Conformational Isomerization ◽  
Torsional Barrier

Interpretation of temperature-dependent low frequency vibrational spectrum of solid-state benzoic acid dimer

2009 ◽  
Vol 479 (4-6) ◽  
pp. 211-217 ◽  
Author(s):  
Masae Takahashi ◽  
Yoshiyuki Kawazoe ◽  
Yoichi Ishikawa ◽  
Hiromasa Ito
Keyword(s):  
Solid State ◽  
Vibrational Spectrum ◽  
Benzoic Acid ◽  
Low Frequency ◽  
Temperature Dependent

scholarly journals Diverse Coordination Numbers and Geometries in Pyridyl Adducts of Lanthanide(III) Complexes Based on β-Diketonate

Inorganics ◽  
2021 ◽  
Vol 9 (10) ◽  
pp. 74
Author(s):  
Franz A. Mautner ◽  
Florian Bierbaumer ◽  
Roland C. Fischer ◽  
Ana Torvisco ◽  
Ramon Vicente ◽  
...  
Keyword(s):  
Rare Earth ◽  
Solid State ◽  
Quantum Yield ◽  
Rare Earth Complexes ◽  
Luminescence Spectra ◽  
Excitation Wavelength ◽  
Coordination Numbers ◽  
State Luminescence

Ten mononuclear rare earth complexes of formula [La(btfa)3(H2O)2] (1), [La(btfa)3(4,4′-Mt2bipy)] (2), [La(btfa)3(4,4′-Me2bipy)2] (3), [La(btfa)3(5,5′-Me2bipy)2] (4), [La(btfa)3(terpy)] (5), [La(btfa)3(phen)(EtOH)] (6), [La(btfa)3(4,4′-Me2bipy)(EtOH)] (7), [La(btfa)3(2-benzpy)(MeOH)] (8), [Tb(btfa)3(4,4′-Me2bipy)] (9) and (Hpy)[Eu(btfa)4] (10), where btfa = 4,4,4-trifuoro-1-phenylbutane-1,3-dionato anion, 4,4′-Mt2bipy = 4,4′-dimethoxy-2,2′-bipyridine, 4,4′-Me2bipy = 4,4′-dimethyl-2,2′-bipyridine, 5,5′-Me2bipy = 5,5′-dimethyl-2,2′-bipyridine, terpy = 2,2′:6′,2′-terpyridine, phen = 1,10-phenathroline, 2-benzpy = 2-(2-pyridyl)benzimidazole, Hpy = pyridiniumH+ cation) have been synthesized and structurally characterized. The complexes display coordination numbers (CN) eight for 1, 2, 9, 10, nine for 5, 6, 7, 8 and ten for 3 and 4. The solid-state luminescence spectra of Tb-9 and Eu-10 complexes showed the same characteristic bands predicted from the Tb(III) and Eu(III) ions. The Overall Quantum Yield measured (ϕTOT) at the excitation wavelength of 371 nm for both compounds yielded 1.04% for 9 and up to 34.56% for 10.

Synthesis, photoluminescence and Judd–Ofelt analysis of red LiGd5P2O13 : Eu3+ phosphors for white LEDs

RSC Advances ◽  
2015 ◽  
Vol 5 (67) ◽  
pp. 54622-54628 ◽  
Author(s):  
Xinguo Zhang ◽  
Liya Zhou ◽  
Qi Pang ◽  
Menglian Gong
Keyword(s):  
Thermal Stability ◽  
Solid State ◽  
Quantum Yield ◽  
Solid State Reaction ◽  
Red Light ◽  
Solid State Reaction Method ◽  
Reaction Method ◽  
White Leds ◽  
Good Thermal Stability ◽  
Red Phosphors

LiGd5P2O13 : Eu3+ red phosphors were prepared by solid-state reaction method. Phosphors could be efficiently excited by NUV/blue light and emit pure-red light. LiGd5P2O13 : Eu3+ shows good thermal stability with quantum yield of 46.5%.

Facile preparation of solid-state fluorescent carbon dots with high fluorescence quantum yield and application in rapid latent fingerprints detection

2021 ◽  
Author(s):  
Hai-Jiao Wang ◽  
Wan-Yi Hou ◽  
Jing Kang ◽  
Xin-Yu Zhai ◽  
Hongli Chen ◽  
...  
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Latent Fingerprints ◽  
Energy Resonance ◽  
Facile Preparation ◽  
High Fluorescence ◽  
Fluorescent Carbon Dots ◽  
High Fluorescence Quantum Yield ◽  
Resonance Transfer

Due to the direct π - π interaction and excessive energy resonance transfer, it is very challenging to prepare CDs with high fluorescence quantum yield (QY) in solid state. In...

Solid State NMR Studies of the Adsorbed States of Formic Acid on Y Zeolites

1980 ◽  
Vol 3 ◽  
Author(s):  
T. Michael Duncan ◽  
Robert W. Vaughan
Keyword(s):  
Solid State ◽  
Formic Acid ◽  
Solid State Nmr ◽  
Double Resonance ◽  
Chemical Shift Anisotropy ◽  
Surface States ◽  
Cross Polarization ◽  
Nmr Studies ◽  
Y Zeolites ◽  
Nmr Techniques

ABSTRACTSeveral multiple-pulse double-resonance NMR techniques have been applied to isolate and characterize the spectra of the adsorbed states of formic acid on two Y zeolites. The two surface states, bidentatT3 and ynidentate, possess different motional properties and 13C - H cross-polarization techniques may be used to separate the spectra. The 13C chemical shift anisotropy is founa to iorrelate with the symmetry of the formate species. The H spectrum of the carbonyl hydrogen, selectively observed with the dipolardifference method, indicates that this hydrogen becomes more acidic upon adsorption.

Solid-state thiolate-stabilized copper nanoclusters with ultrahigh photoluminescence quantum yield for white light-emitting devices

Nanoscale ◽  
2020 ◽  
Vol 12 (29) ◽  
pp. 15791-15799 ◽  
Author(s):  
Hao-Hua Deng ◽  
Qiong-Qiong Zhuang ◽  
Kai-Yuan Huang ◽  
Paramasivam Balasubramanian ◽  
Zhen Lin ◽  
...  
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
White Light ◽  
Copper Nanoclusters ◽  
Light Emitting ◽  
Aggregation Induced Emission ◽  
Emission Properties ◽  
Light Emitting Devices ◽  
Photoluminescence Quantum Yield

White-light-emitting devices are successfully fabricated by using solid-state copper nanoclusters as the sole phosphors with aggregation-induced emission properties.

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