scholarly journals Ideal glass transitions in thin films: An energy landscape perspective

2003 ◽  
Vol 119 (4) ◽  
pp. 1897-1900 ◽  
Author(s):  
Thomas M. Truskett ◽  
Venkat Ganesan
Author(s):  
C. Austen Angell

We describe basic phenomenology in the physics of supercooling liquids at constant volume (most simulations), and at constant pressure (most laboratory experiments) before focusing attention on the exceptional cases that exhibit liquid–liquid phase transitions on constant–pressure cooling. We give evidence for point defects in glasses and liquids near T g . Models based on defects predict transitions with density gaps in constant–pressure systems. We describe the energy landscape representation of such systems. Water, in these terms, is post–critical, and its nearly ideal glass formation can be related to nucleation–free protein ‘funnel–folding’. For nucleated folding of proteins, a pseudo–gap should be present. Experimental methods of distinguishing between alternative folding scenarios are described.


2015 ◽  
Vol 5 (1) ◽  
Author(s):  
Tae Heon Kim ◽  
Jong-Gul Yoon ◽  
Seung Hyub Baek ◽  
Woong-kyu Park ◽  
Sang Mo Yang ◽  
...  

1997 ◽  
Vol 251 (1-2) ◽  
pp. 138-141
Author(s):  
G. Nakielski ◽  
M. Kaufmann ◽  
A. Rickertsen ◽  
M. Baumann ◽  
M. Schilling ◽  
...  

2015 ◽  
Vol 9 (3) ◽  
pp. 157-168 ◽  
Author(s):  
Johann Schön

Nanomaterials bridge the gaps between crystalline materials, thin films, and molecules, and are of great importance in the design of new classes of materials, since the existence of many modifications of a nano-object for the same overall composition allows us to tune the properties of the nanomaterial. However, the structural analysis of nano-size systems is often difficult and their structural stability is frequently relatively low. Thus, a study of their energy landscape is needed to determine or predict possible structures, and analyse their stability, via the determination of the minima on the landscape and the generalized barriers separating them. In this contribution, we introduce the major concepts of energy landscapes for chemical systems, and present summaries of four applications to nano-materials: a MgO monolayer on a sapphire substrate, possible quasitwo- dimensional carbon-silicon networks, the ab initio energy landscape of Cu4Ag4-clusters, and the possible arrangements of ethane molecules on an ideally smooth substrate.


2010 ◽  
Vol 43 (23) ◽  
pp. 9874-9880 ◽  
Author(s):  
Jane E. G. Lipson ◽  
Scott T. Milner

Author(s):  
L.J. Chen ◽  
Y.F. Hsieh

One measure of the maturity of a device technology is the ease and reliability of applying contact metallurgy. Compared to metal contact of silicon, the status of GaAs metallization is still at its primitive stage. With the advent of GaAs MESFET and integrated circuits, very stringent requirements were placed on their metal contacts. During the past few years, extensive researches have been conducted in the area of Au-Ge-Ni in order to lower contact resistances and improve uniformity. In this paper, we report the results of TEM study of interfacial reactions between Ni and GaAs as part of the attempt to understand the role of nickel in Au-Ge-Ni contact of GaAs.N-type, Si-doped, (001) oriented GaAs wafers, 15 mil in thickness, were grown by gradient-freeze method. Nickel thin films, 300Å in thickness, were e-gun deposited on GaAs wafers. The samples were then annealed in dry N2 in a 3-zone diffusion furnace at temperatures 200°C - 600°C for 5-180 minutes. Thin foils for TEM examinations were prepared by chemical polishing from the GaA.s side. TEM investigations were performed with JE0L- 100B and JE0L-200CX electron microscopes.


Author(s):  
R. C. Moretz ◽  
G. G. Hausner ◽  
D. F. Parsons

Use of the electron microscope to examine wet objects is possible due to the small mass thickness of the equilibrium pressure of water vapor at room temperature. Previous attempts to examine hydrated biological objects and water itself used a chamber consisting of two small apertures sealed by two thin films. Extensive work in our laboratory showed that such films have an 80% failure rate when wet. Using the principle of differential pumping of the microscope column, we can use open apertures in place of thin film windows.Fig. 1 shows the modified Siemens la specimen chamber with the connections to the water supply and the auxiliary pumping station. A mechanical pump is connected to the vapor supply via a 100μ aperture to maintain steady-state conditions.


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