The kinetics of mixing and the fluctuation theorem in ideal mixtures of two-component model fluids

2003 ◽  
Vol 119 (4) ◽  
pp. 2144-2146 ◽  
Author(s):  
András Baranyai
Keyword(s):  
Fluctuation Theorem ◽  
Component Model ◽  
Two Component ◽  
Kinetics Of ◽  
Model Fluids

scholarly journals Kinetics of substrate hydrolysis and inhibition by mipafox of paraoxon-preinhibited hen brain esterase activity

1986 ◽  
Vol 236 (2) ◽  
pp. 503-507 ◽  
Author(s):  
C D Carrington ◽  
M B Abou-Donia
Keyword(s):  
Kinetic Parameters ◽  
Organophosphorus Compounds ◽  
Model Fit ◽  
Component Model ◽  
Low Concentrations ◽  
Two Component ◽  
High Concentrations ◽  
Kinetics Of ◽  
Hydrolysis Of ◽  
Organophosphorus Inhibitor

For the purpose of assessing the neurotoxic potential of organophosphorus compounds, it has been determined that paraoxon-preinhibited hen brain has both neurotoxicant (mipafox)-sensitive (neurotoxic esterase; NTE) and -insensitive esterase components. Several experiments designed to investigate the kinetic parameters governing the reaction of these esterases with two substrates and one organophosphorus inhibitor are presented. First, kinetic parameters for the hydrolysis of phenyl valerate and phenyl phenylacetate were measured. At 37 degrees C, the Km values of NTE for phenyl valerate and phenyl phenylacetate were found to be about 1.4 × 10(-3) and 1.6 × 10(-4) M respectively. At 25 degrees C, the Km of NTE for phenyl valerate was determined to be about 2.4 × 10(-3) M. Secondly, the kinetic constants of NTE for mipafox were measured at both 25 degrees C and 37 degrees C. With either phenyl valerate or phenyl phenylacetate as substrate, the Km at 37 degrees C was determined to be about 1.8 × 10(-4) M, and the phosphorylation constant (k2) was about 1.1 min-1. For phenyl valerate only, the Km at 25 degrees C was found to be about 6 × 10(-4) M, and the k2 was about 0.7 min-1. The data obtained at 25 degrees C were analysed by using a two-component model without formation of Michaelis complex, a two-component model with formation of Michaelis complex on the second component (NTE), or a three-component model without formation of Michaelis complex. The fact that the Michaelis model fit the data significantly better than either of the other two models indicates that the higher apparent Ki values that occur with low concentrations of mipafox are due to formation of Michaelis complex at high concentrations, rather than because of the presence of two NTE isoenzymes, as has been suggested by other investigators.

The Effect of H2 Dilution on the Stability of a-Si:H based Solar Cells

1994 ◽  
Vol 336 ◽  
Author(s):  
Liyou Yang ◽  
Liang-Fan Chen
Keyword(s):  
Solar Cells ◽  
Substrate Temperature ◽  
Structural Properties ◽  
Recovery Process ◽  
The Other ◽  
Component Model ◽  
Device Stability ◽  
Two Component ◽  
The Stability ◽  
Kinetics Of

ABSTRACTWe have systematically investigated the effect of H2 dilution on the stability of a-Si:H based solar cells. The results clearly show that the device stability against light soaking improves substantially with increasing H2 dilution until a threshold is reached. Beyond this threshold which depends on the substrate temperature, the stability no longer changes with further increase in H2 dilution. On the other hand, at a given ratio of H2 to the reactant gases, the device stability generally improves with increasing substrate temperature. Multi-step light soaking experiments have shown that devices made with H2 dilution saturate much faster (∼100 hours) under one-sun illumination and exhibit little overshoot effect in the recovery process, in sharp contrast to devices made without H2 dilution. Based on the simple two-component model for defect kinetics, these observations and the fact that the apparent saturation time coincides with the time constant of the “fast” defects strongly suggest that negligible amount of “slow” defects exist in materials made with H2 dilution. While H2 dilution generally suppresses the formation of microstructure giving rise to dihydride bonding and microvoids, the differences in the kinetics of light induced degradation cannot always be traced to obvious differences in these structural properties.

Radiometric Chronology of Neh–nar Glacier, Kashmir

1982 ◽  
Vol 28 (98) ◽  
pp. 91-105 ◽  
Author(s):  
V. N. Nijampurkar ◽  
N. Bhandari ◽  
C. P. Vohra ◽  
V. Krishnan
Keyword(s):  
Average Rate ◽  
Component Model ◽  
Vertical Profiles ◽  
Kashmir Valley ◽  
Movement Rate ◽  
Accumulation Zone ◽  
Core Samples ◽  
Surface Samples ◽  
Two Component

AbstractSurface and core samples of Neh–nar Glacier in the Kashmir Valley have been analysed for the radionuclides 32Si. 210Pb, 40K, and 137Cs. The lateral and vertical profiles (at an altitude of about 4 140 m) reveal:(1)32Si activity decreasing slowly from the accumulation zone to 4 050 m altitude and then abruptly towards the snout.(2)Five zones of alternating high and low 210Pb activity in the surface samples.(3)An horizon at between 2 and 3 m depth containing 210Pb activity above natural levels. This horizon is also associated with 137Cs and a maximum in total ß activity.The ice samples have been dated on the basis of a simplified two–component model, the “fresh“contribution determined by 2l0Pb and the old component by 32Si. The following conclusions can be drawn from these observations:(1)The model age of the snout ice is c. 850 years.(2)The average rate of ice movement in the lower glacier is about 2 m/year, which compares well with the annual movement rate of 2.65 m/year observed since 1974.

scholarly journals Estimation of Galactic Model Parameters by Interval Method

1996 ◽  
Vol 169 ◽  
pp. 713-714
Author(s):  
S. A. Kutuzov
Keyword(s):  
Mutual Interaction ◽  
Component Model ◽  
Model Parameters ◽  
Interval Method ◽  
Two Component ◽  
The Galaxy ◽  
Galactic Model

The interval method of estimating model parameters (MPs) for the Galaxy was suggested earlier (Kutuzov 1988). Intervals are proposed to be used both for observational estimates of galactic parameters (GPs) and for the values of MPs. In this work we consider a model as a tool for studying mutual interaction of GPs. Two-component model is considered (Kutuzov, Ossipkov 1989). We have to estimate the array P of eight MPs.

scholarly journals A Two‐Component Model for the Light Curves of Hypernovae

2003 ◽  
Vol 593 (2) ◽  
pp. 931-940 ◽  
Author(s):  
Keiichi Maeda ◽  
Paolo A. Mazzali ◽  
Jingsong Deng ◽  
Ken’ichi Nomoto ◽  
Yuzuru Yoshii ◽  
...  
Keyword(s):  
Light Curves ◽  
Component Model ◽  
Two Component

Two-Component Model of Chemyon-Oriented Behaviors in Korea

2002 ◽  
Vol 33 (3) ◽  
pp. 332-345 ◽  
Author(s):  
Sang-Chin Choi ◽  
Suk-Jae Lee
Keyword(s):  
Component Model ◽  
Two Component
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