scholarly journals Self-affine and mound roughness effects on the double-layer charge capacitance

2002 ◽  
Vol 92 (12) ◽  
pp. 7175-7179 ◽  
Author(s):  
G. Palasantzas ◽  
G. M. E. A. Backx
Langmuir ◽  
2012 ◽  
Vol 28 (28) ◽  
pp. 10610-10619 ◽  
Author(s):  
Fraser Mole ◽  
Jue Wang ◽  
Daniel A. Clayton ◽  
Cailing Xu ◽  
Shanlin Pan

2017 ◽  
Vol 31 (01) ◽  
pp. 1650431 ◽  
Author(s):  
Ning Sun ◽  
Dilip Gersappe

We use a Lattice Boltzmann Model (LBM) in order to simulate diffuse-charge dynamics in Electric Double Layer Capacitors (EDLCs). Simulations are carried out for both the charge and the discharge processes on 2D systems of complex random electrode geometries (pure random, random spheres and random fibers). The steric effect of concentrated solutions is considered by using a Modified Poisson–Nernst–Planck (MPNP) equations and compared with regular Poisson–Nernst–Planck (PNP) systems. The effects of electrode microstructures (electrode density, electrode filler morphology, filler size, etc.) on the net charge distribution and charge/discharge time are studied in detail. The influence of applied potential during discharging process is also discussed. Our studies show how electrode morphology can be used to tailor the properties of supercapacitors.


2012 ◽  
Vol 48 (2) ◽  
pp. 459-462 ◽  
Author(s):  
K. Ishibashi ◽  
Z. Andjelic ◽  
Y. Takahashi ◽  
T. Takamatsu ◽  
T. Fukuzumi ◽  
...  

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