Electron transfer in the D–B–A model system: A vibronic analysis

2002 ◽  
Vol 117 (3) ◽  
pp. 1279-1289 ◽  
Author(s):  
Giovanni Villani
Keyword(s):  
Electron Transfer ◽  
Model System ◽  
System A ◽  
Vibronic Analysis

The use of a silica-based heat sink to “uncouple” the matrix-assisted laser desorption/ionization (MALDI) mechanism

2011 ◽  
Vol 89 (4) ◽  
pp. 446-460 ◽  
Author(s):  
E. Lourantos ◽  
O. M. Ramirez ◽  
A. E. Giannakopulos ◽  
K. A. Beran ◽  
Peter J. Derrick ◽  
...  
Keyword(s):  
Gas Phase ◽  
Heat Sink ◽  
Model System ◽  
Model Systems ◽  
Laser Desorption Ionization ◽  
System A ◽  
The Matrix ◽  
Pass Through ◽  
Maldi Mechanism ◽  
Silicon Based

The relationships between ion yield(s) as a function of desorption alone and (or) ionization was investigated using two model systems. In the first model system, a carbohydrate (2,3,6-tri-O-methyl-β-cyclodextrin, TMBCD), which could be directly laser desorbed, was analyzed with and without a silicon-based heat sink compound (HSC). The HSC allowed heat to pass through but obstructed the flow of charge. In the second model system, a peptide (substance P), which ccould not be laser desorbed, was analyzed under similar conditions. The ion yield of TMBCD under either system of heat conductivity was similar, whereas the ion yield of the peptide with the heat sink was negligible. Compounds that are predominately cationized either in the gas phase or preformed in solution give an ion yield that is not dependent upon the surface conditions, whereas compounds that are not ordinarily cationized are affected by the emission of electrons from the metal surface.

Fog Simulations Based on Multi-Model System: A Feasibility Study

2011 ◽  
Vol 169 (5-6) ◽  
pp. 941-960 ◽  
Author(s):  
Chune Shi ◽  
Lei Wang ◽  
Hao Zhang ◽  
Su Zhang ◽  
Xueliang Deng ◽  
...  
Keyword(s):  
Feasibility Study ◽  
Model System ◽  
System A

L2,3-edges absorption spectra of a 2D complex system: a theoretical modelling

2016 ◽  
Vol 18 (40) ◽  
pp. 28110-28116 ◽  
Author(s):  
S. Carlotto ◽  
M. Sambi ◽  
F. Sedona ◽  
A. Vittadini ◽  
J. Bartolomé ◽  
...  
Keyword(s):  
Complex System ◽  
Electron Transfer ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Absorption Spectra ◽  
Ground State ◽  
Reduction Reaction ◽  
Theoretical Modelling ◽  
Electron Transfer Pathway ◽  
System A

Ground state theoretical outcomes pertaining to FePc (I) and FePc(η2-O2) (II) provide an intimate understanding of the electron transfer pathway ruling the catalytic oxygen reduction reaction of I on Ag(110).

Nonlocal polarizability density of a model system: A homogeneous electron gas at T=0

1993 ◽  
Vol 98 (4) ◽  
pp. 3066-3075 ◽  
Author(s):  
R. Nimalakirthi ◽  
K. L. C. Hunt
Keyword(s):  
Electron Gas ◽  
Model System ◽  
System A
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