scholarly journals Space-selective valence state manipulation of transition metal ions inside glasses by a femtosecond laser

2001 ◽  
Vol 79 (22) ◽  
pp. 3567-3569 ◽  
Author(s):  
Jianrong Qiu ◽  
Congshan Zhu ◽  
Takayuki Nakaya ◽  
Jinhai Si ◽  
Kazuo Kojima ◽  
...  
Keyword(s):  
Transition Metal ◽  
Femtosecond Laser ◽  
Metal Ions ◽  
Valence State ◽  
Transition Metal Ions

The coordination state and valence state of selected transition metal ions in SiO2–B2O3 xerogels

2002 ◽  
Vol 311 (1) ◽  
pp. 10-23 ◽  
Author(s):  
Andrzej M. Kłonkowski ◽  
Dominika Dunajska ◽  
Mariusz Biczkowski ◽  
Anna Jankowska-Frydel
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Valence State ◽  
Transition Metal Ions ◽  
Coordination State

Coordination and valence state of transition metal ions in alkali-borate glasses

2011 ◽  
Vol 33 (12) ◽  
pp. 1984-1988 ◽  
Author(s):  
A. Terczyńska-Madej ◽  
K. Cholewa-Kowalska ◽  
M. Łączka
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Valence State ◽  
Transition Metal Ions ◽  
Borate Glasses ◽  
Alkali Borate Glasses

Doping transition metal ions as a method for enhancement of ablation rate in femtosecond laser irradiation of silicate glass

2014 ◽  
Vol 12 (12) ◽  
pp. 121402-121406 ◽  
Author(s):  
Juqiang Fang Juqiang Fang ◽  
Lan Jiang Lan Jiang ◽  
Qiang Cao Qiang Cao ◽  
Yanping Yuan Yanping Yuan ◽  
Liangti Qu Liangti Qu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Femtosecond Laser ◽  
Metal Ions ◽  
Laser Irradiation ◽  
Silicate Glass ◽  
Transition Metal Ions ◽  
Ablation Rate ◽  
Femtosecond Laser Irradiation

HREM Study of electron-induced surface radiation damage in ReO3

1991 ◽  
Vol 49 ◽  
pp. 636-637
Author(s):  
R. Ai ◽  
H.-J. Fan ◽  
L. D. Marks
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Metal Oxides ◽  
Electron Irradiation ◽  
Transition Metal Oxides ◽  
Carbon Film ◽  
Transition Metal Ions ◽  
Surface Radiation ◽  
Valence Transition ◽  
Electron Microscopes

It has been known for a long time that electron irradiation induces damage in maximal valence transition metal oxides such as TiO2, V2O5, and WO3, of which transition metal ions have an empty d-shell. This type of damage is excited by electronic transition and can be explained by the Knoteck-Feibelman mechanism (K-F mechanism). Although the K-F mechanism predicts that no damage should occur in transition metal oxides of which the transition metal ions have a partially filled d-shell, namely submaximal valence transition metal oxides, our recent study on ReO3 shows that submaximal valence transition metal oxides undergo damage during electron irradiation.ReO3 has a nearly cubic structure and contains a single unit in its cell: a = 3.73 Å, and α = 89°34'. TEM specimens were prepared by depositing dry powders onto a holey carbon film supported on a copper grid. Specimens were examined in Hitachi H-9000 and UHV H-9000 electron microscopes both operated at 300 keV accelerating voltage. The electron beam flux was maintained at about 10 A/cm2 during the observation.

Synthesis, Spectral and Antimicrobial Investigation of 2-(Naphthalenel-ylamino)-2- Phenylacetonitrile and 1, 10-Phenanthroline with Five Divalent Transition Metal Ions

2019 ◽  
Vol 10 (01) ◽  
Author(s):  
Mohammed Al-Amery1 ◽  
Ashraf Saad Rasheed ◽  
Dina A. Najeeb
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Transition Metal Ions ◽  
Molar Conductance ◽  
Octahedral Geometry ◽  
Mixed Ligand ◽  
Gram Negative Bacteria ◽  
Magnetic Studies ◽  
Gram Positive Bacteria

Five new mixed ligand metal complexes have been synthesized by the reaction of divalent transition metal ions (Hg, Ni, Zn, Cu and Cd) with 2-(naphthalen-l-ylamino)-2-phenylacetonitrile (L1 ) and 1,10-phenanthroline (L2). The coordination likelihood of the two ligands toward metal ions has been suggested in the light of elemental analysis, UV-Vis spectra, FTIR, 1H-NMR, flam atomic absorption, molar conductance and magnetic studies. Results data suggest that the octahedral geometry for all the prepared complexes. Antibacterial examination of synthesized complexes in vitro was performed against four bacterias. Firstly, Gram-negative bacteria namely, Pseudomonas aerugin and Escherichia. Secondly, Gram-positive bacteria namely, Bacillus subtilis, Staphylococcuaurouss. Results data exhibit that the synthesized complexes exhibited more biological activity than tetracycline pharmaceutical.

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