Quantum effects in liquid water: Path-integral simulations of a flexible and polarizable ab initio model

2001 ◽  
Vol 115 (16) ◽  
pp. 7622-7628 ◽  
Author(s):  
Harry A. Stern ◽  
B. J. Berne
Keyword(s):  
Ab Initio ◽  
Path Integral ◽  
Liquid Water ◽  
Quantum Effects ◽  
Liquid Water Path ◽  
Water Path

scholarly journals MBL drizzle properties and their impact on cloud property retrievals

2015 ◽  
Vol 8 (4) ◽  
pp. 4307-4323
Author(s):  
P. Wu ◽  
X. Dong ◽  
B. Xi
Keyword(s):  
Liquid Water ◽  
Cloud Droplet ◽  
Number Concentration ◽  
Effective Radius ◽  
Liquid Water Path ◽  
Water Path ◽  
Cloud Property ◽  
Annual Means ◽  
Mean Differences ◽  
The Impact

Abstract. In this study, we retrieve and document drizzle properties, and investigate the impact of drizzle on cloud property retrievals from ground-based measurements at the ARM Azores site from June 2009 to December 2010. For the selected cloud and drizzle samples, the drizzle occurrence is 42.6% with a maximum of 55.8% in winter and a minimum of 35.6% in summer. The annual means of drizzle liquid water path LWPd, effective radius rd, and number concentration Nd for the rain (virga) samples are 5.48 (1.29) g m−2, 68.7 (39.5) μm, and 0.14 (0.38) cm−3. The seasonal mean LWPd values are less than 4% of the MWR-retrieved LWP values. The annual mean differences in cloud-droplet effective radius with and without drizzle are 0.12 and 0.38 μm, respectively, for the virga and rain samples. Therefore, we conclude that the impact of drizzle on cloud property retrievals is insignificant at the ARM Azores site.

Variational Assimilation of Cloud Liquid/Ice Water Path and Its Impact on NWP

2015 ◽  
Vol 54 (8) ◽  
pp. 1809-1825 ◽  
Author(s):  
Yaodeng Chen ◽  
Hongli Wang ◽  
Jinzhong Min ◽  
Xiang-Yu Huang ◽  
Patrick Minnis ◽  
...  
Keyword(s):  
Data Assimilation ◽  
Liquid Water ◽  
Weather Prediction ◽  
Wrf Model ◽  
Liquid Water Path ◽  
Cloud Liquid Water ◽  
Water Path ◽  
Ice Water Path ◽  
Ice Water ◽  
The Impact

AbstractAnalysis of the cloud components in numerical weather prediction models using advanced data assimilation techniques has been a prime topic in recent years. In this research, the variational data assimilation (DA) system for the Weather Research and Forecasting (WRF) Model (WRFDA) is further developed to assimilate satellite cloud products that will produce the cloud liquid water and ice water analysis. Observation operators for the cloud liquid water path and cloud ice water path are developed and incorporated into the WRFDA system. The updated system is tested by assimilating cloud liquid water path and cloud ice water path observations from Global Geostationary Gridded Cloud Products at NASA. To assess the impact of cloud liquid/ice water path data assimilation on short-term regional numerical weather prediction (NWP), 3-hourly cycling data assimilation and forecast experiments with and without the use of the cloud liquid/ice water paths are conducted. It is shown that assimilating cloud liquid/ice water paths increases the accuracy of temperature, humidity, and wind analyses at model levels between 300 and 150 hPa after 5 cycles (15 h). It is also shown that assimilating cloud liquid/ice water paths significantly reduces forecast errors in temperature and wind at model levels between 300 and 150 hPa. The precipitation forecast skills are improved as well. One reason that leads to the improved analysis and forecast is that the 3-hourly rapid update cycle carries over the impact of cloud information from the previous cycles spun up by the WRF Model.

Understanding the Extratropical Liquid Water Path Feedback in Mixed-Phase Clouds with an Idealized Global Climate Model

2022 ◽  
pp. 1-48
Author(s):  
Yi Ming
Keyword(s):  
Water Content ◽  
Liquid Water ◽  
Climate Model ◽  
Global Climate Model ◽  
Cloud Water ◽  
Mixed Phase ◽  
Liquid Water Path ◽  
Water Path ◽  
Cloud Water Content ◽  
Mixed Phase Clouds

Abstract A negative shortwave cloud feedback associated with higher extratropical liquid water content in mixed-phase clouds is a common feature of global warming simulations, and multiple mechanisms have been hypothesized. A set of process-level experiments performed with an idealized global climate model (a dynamical core with passive water and cloud tracers and full Rotstayn-Klein single-moment microphysics) show that the common picture of the liquid water path (LWP) feedback in mixed-phase clouds being controlled by the amount of ice susceptible to phase change is not robust. Dynamic condensate processes—rather than static phase partitioning—directly change with warming, with varied impacts on liquid and ice amounts. Here, three principal mechanisms are responsible for the LWP response, namely higher adiabatic cloud water content, weaker liquid-to-ice conversion through the Bergeron-Findeisen process, and faster melting of ice and snow to rain. Only melting is accompanied by a substantial loss of ice, while the adiabatic cloud water content increase gives rise to a net increase in ice water path (IWP) such that total cloud water also increases without an accompanying decrease in precipitation efficiency. Perturbed parameter experiments with a wide range of climatological LWP and IWP demonstrate a strong dependence of the LWP feedback on the climatological LWP and independence from the climatological IWP and supercooled liquid fraction. This idealized setup allows for a clean isolation of mechanisms and paints a more nuanced picture of the extratropical mixed-phase cloud water feedback than simple phase change.

scholarly journals The Impacts of Atmospheric and Surface Parameters on Long-Term Variations in the Planetary Albedo

2018 ◽  
Vol 31 (21) ◽  
pp. 8705-8718 ◽  
Author(s):  
Bida Jian ◽  
Jiming Li ◽  
Guoyin Wang ◽  
Yongli He ◽  
Ying Han ◽  
...  
Keyword(s):  
Liquid Water ◽  
Surface Albedo ◽  
Cloud Fraction ◽  
Liquid Water Path ◽  
Water Path ◽  
Ice Water Path ◽  
Planetary Albedo ◽  
Ice Water ◽  
Long Term Variations

Planetary albedo (PA; shortwave broadband albedo) and its long-term variations, which are controlled in a complex way by various atmospheric and surface properties, play a key role in controlling the global and regional energy budget. This study investigates the contributions of different atmospheric and surface properties to the long-term variations of PA based on 13 years (2003–15) of albedo, cloud, and ice coverage datasets from the Clouds and the Earth’s Radiant Energy System (CERES) Single Scanner Footprint edition 4A product, vegetation product from Moderate Resolution Imaging Spectroradiometer (MODIS), and surface albedo product from the Cloud, Albedo, and Radiation dataset, version 2 (CLARA-A2). According to the temporal correlation analysis, statistical results indicate that variations in PA are closely related to the variations of cloud properties (e.g., cloud fraction, ice water path, and liquid water path) and surface parameters (e.g., ice/snow percent coverage and normalized difference vegetation index), but their temporal relationships vary among the different regions. Generally, the stepwise multiple linear regression models can capture the observed PA anomalies for most regions. Based on the contribution calculation, cloud fraction dominates the variability of PA in the mid- and low latitudes while ice/snow percent coverage (or surface albedo) dominates the variability in the mid- and high latitudes. Changes in cloud liquid water path and ice water path are the secondary dominant factor over most regions, whereas change in vegetation cover is the least important factor over land. These results verify the effects of atmospheric and surface factors on planetary albedo changes and thus may be of benefit for improving the parameterization of the PA and determining the climate feedbacks.

Reconciling and Validating the Cloud Thickness and Liquid Water Path Tendencies Proposed by R. Wood and J. J. van der Dussen et al.

2015 ◽  
Vol 72 (5) ◽  
pp. 2033-2040 ◽  
Author(s):  
Mohamed S. Ghonima ◽  
Joel R. Norris ◽  
Thijs Heus ◽  
Jan Kleissl
Keyword(s):  
Boundary Layer ◽  
Liquid Water ◽  
Mixed Boundary ◽  
Liquid Water Path ◽  
Water Path ◽  
Large Eddy ◽  
Heat And Moisture ◽  
Cloud Thickness ◽  
Detailed Derivation ◽  
Good Agreement

Abstract A detailed derivation of stratocumulus cloud thickness and liquid water path tendencies as a function of the well-mixed boundary layer mass, heat, and moisture budget equations is presented. The derivation corrects an error in the cloud thickness tendency equation derived by R. Wood to make it consistent with the liquid water path tendency equation derived by J. J. van der Dussen et al. The validity of the tendency equations is then tested against the output of large-eddy simulations of a typical stratocumulus-topped boundary layer case and is found to be in good agreement.

scholarly journals Cloud optical thickness and liquid water path. Does the <i>k</i> coefficient vary with droplet concentration?

2011 ◽  
Vol 11 (2) ◽  
pp. 5173-5215
Author(s):  
J.-L. Brenguier ◽  
F. Burnet ◽  
O. Geoffroy
Keyword(s):  
Correction Factor ◽  
Optical Thickness ◽  
Liquid Water ◽  
General Circulation ◽  
Field Experiments ◽  
General Circulation Models ◽  
Light Extinction ◽  
Liquid Water Path ◽  
Water Path ◽  
Droplet Concentration

Abstract. Cloud radiative transfer calculations in general circulation models involve a link between cloud microphysical and optical properties. Indeed, the liquid water content expresses as a function of the mean volume droplet radius, while the light extinction is a function of their mean surface radius. There is a small difference between these two parameters because of the droplet spectrum width. This issue has been addressed by introducing an empirical multiplying correction factor to the droplet concentration. Analysis of in situ sampled data, however, revealed that the correction factor decreases when the concentration increases, hence partially mitigating the aerosol indirect effect. Five field experiments are reanalyzed here, in which standard and upgraded versions of the droplet spectrometer were used to document shallow cumulus and stratocumulus topped boundary layers. They suggest that the standard probe noticeably underestimates the correction factor compared to the upgraded versions. The analysis is further refined to demonstrate that the value of the correction factor derived by averaging values calculated locally along the flight path overestimates the value derived from liquid water path and optical thickness of a cloudy column, and that there is no detectable correlation between the correction factor and the droplet concentration. It is also shown that the droplet concentration dilution by entrainment-mixing after CCN activation is significantly stronger in shallow cumuli than in stratocumulus layers. These various effects are finally combined to produce the best estimate of the correction factor to use in general circulation models.

scholarly journals A New Conceptual Model for Adiabatic Fog

2021 ◽  
Author(s):  
Felipe Toledo ◽  
Martial Haeffelin ◽  
Eivind Wærsted ◽  
Jean-Charles Dupont
Keyword(s):  
Life Cycle ◽  
Conceptual Model ◽  
Real Time ◽  
Liquid Water ◽  
Critical Value ◽  
Liquid Water Path ◽  
Horizontal Visibility ◽  
Fog Water ◽  
Water Path ◽  
The Way

Abstract. We propose a new paradigm to describe the temporal evolution of continental fog layers. This paradigm defines fog as a layer saturated from the surface to a known upper boundary, and whose liquid water path (LWP) exceeds a critical value, the critical liquid water path (CLWP). When the LWP is less than the CLWP the fog water cannot extend all the way to the surface, leading to a surface horizontal visibility greater than 1 km. On the opposite, when the LWP is larger than the CLWP, the fog water extends all the way to the surface, inducing a horizontal visibility less than 1 km. The excess water with respect to the critical value is then defined as the reservoir liquid water path (RLWP). The new fog paradigm is formulated as a conceptual model that relates the liquid water path of adiabatic fog with its thickness and surface liquid water content, and allows the critical and reservoir liquid water paths to be computed. Both variables can be tracked in real time using vertical profiling measurements, enabling a real time diagnostic of fog status. The conceptual model is tested using data from seven years of measurements performed at the SIRTA observatory, combining cloud radar, microwave radiometer, ceilometer, scatterometer and weather station measurements. In this time period we found 80 fog events with reliable measurements, with 56 of these lasting more than three hours. The paper presents the conceptual model and its capability to derive the LWP from the fog CTH and surface horizontal visibility with an RMS uncertainty of 10.5 g m−2. The impact of fog liquid water path and fog top height variations on fog life cycle (formation to dissipation) is presented based on four case studies, and statistics derived from 56 fog events. Our results show in particular that the reservoir liquid water path is consistently positive during the mature phase of the fog and that it starts to decrease quasi monotonously about one hour before dissipation, reaching a near-zero value at the time of dissipation. The reservoir liquid water path and its time derivative could hence be used as an indicator for life cycle stage and support short range forecasting of fog dissipation.

scholarly journals Ground-based observations of cloud and drizzle liquid water path in stratocumulus clouds

2020 ◽  
Vol 13 (3) ◽  
pp. 1485-1499 ◽  
Author(s):  
Maria P. Cadeddu ◽  
Virendra P. Ghate ◽  
Mario Mech
Keyword(s):  
Liquid Water ◽  
Microwave Radiometer ◽  
Precipitable Water ◽  
Cloud Base ◽  
Radiative Cooling ◽  
Liquid Water Path ◽  
Cell Systems ◽  
Water Path ◽  
Closed Cell ◽  
Stratocumulus Clouds

Abstract. The partition of cloud and drizzle water path in precipitating clouds plays a key role in determining the cloud lifetime and its evolution. A technique to quantify cloud and drizzle water path by combining measurements from a three-channel microwave radiometer (23.8, 30, and 90 GHz) with those from a vertically pointing Doppler cloud radar and a ceilometer is presented. The technique is showcased using 1 d of observations to derive precipitable water vapor, liquid water path, cloud water path, drizzle water path below the cloud base, and drizzle water path above the cloud base in precipitating stratocumulus clouds. The resulting cloud and drizzle water path within the cloud are in good qualitative agreement with the information extracted from the radar Doppler spectra. The technique is then applied to 10 d each of precipitating closed and open cellular marine stratocumuli. In the closed-cell systems only ∼20 % of the available drizzle in the cloud falls below the cloud base, compared to ∼40 % in the open-cell systems. In closed-cell systems precipitation is associated with radiative cooling at the cloud top <-100Wm-2 and a liquid water path >200 g m−2. However, drizzle in the cloud begins to exist at weak radiative cooling and liquid water path >∼150 g m−2. Our results collectively demonstrate that neglecting scattering effects for frequencies at and above 90 GHz leads to overestimation of the total liquid water path of about 10 %–15 %, while their inclusion paves the path for retrieving drizzle properties within the cloud.

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