Resonance Raman intensity analysis of chlorine dioxide dissolved in chloroform: The role of nonpolar solvation

2001 ◽  
Vol 114 (19) ◽  
pp. 8492-8504 ◽  
Author(s):  
Catherine E. Foster ◽  
Bethany P. Barham ◽  
Philip J. Reid
Keyword(s):  
Chlorine Dioxide ◽  
Resonance Raman ◽  
Raman Intensity ◽  
Intensity Analysis ◽  
Nonpolar Solvation

scholarly journals Investigating the Environment-dependent Photophysics of Chlorine Dioxide With Resonance Raman Intensities

1999 ◽  
Vol 19 (1-4) ◽  
pp. 305-309
Author(s):  
Anthony P. Esposito ◽  
Catherine E. Foster ◽  
Philip J. Reid
Keyword(s):  
Excited State ◽  
Gas Phase ◽  
Chlorine Dioxide ◽  
Resonance Raman ◽  
Structural Evolution ◽  
Reaction Dynamics ◽  
Intensity Analysis ◽  
Normal Coordinates ◽  
Raman Intensities ◽  
Asymmetric Stretch

The condensed-phase excited-state reaction dynamics of chlorine dioxide are investigated using resonance Raman intensity analysis. Absolute Raman intensities are measured on resonance with the 2B2–2A2 electronic transition and used to establish the excited-state structural evolution which occurs on the 2A2 surface following photoexcitation. Analysis of the intensities demonstrates that excited-state relaxation occurs along all three normal coordinates; however, only modest evolution is observed along the asymmetric stretch. This limited relaxation stands in contrast to the extensive motion along this coordinate in the gas phase. It is proposed that the initial excited-state structural relaxation serves to define the symmetry of the reaction coordinate and thus the mechanism of Cl production following photolysis of OClO.

Resonance Raman intensity analysis of a dicyanovinyl-azaadamantane: Mode-specific reorganization energies for charge-transfer and locally-excited states

1998 ◽  
Vol 109 (24) ◽  
pp. 10958-10969 ◽  
Author(s):  
Mark Lilichenko ◽  
Dietrich Tittelbach-Helmrich ◽  
Jan W. Verhoeven ◽  
Ian R. Gould ◽  
Anne B. Myers
Keyword(s):  
Charge Transfer ◽  
Excited States ◽  
Resonance Raman ◽  
Raman Intensity ◽  
Intensity Analysis ◽  
Locally Excited ◽  
Reorganization Energies

Resonance Raman intensity analysis of the photochemical hydrogen migration in 1,3,5-cycloheptatriene

1993 ◽  
Vol 97 (49) ◽  
pp. 12691-12699 ◽  
Author(s):  
Philip J. Reid ◽  
Richard A. Mathies ◽  
Andrew P. Shreve
Keyword(s):  
Resonance Raman ◽  
Raman Intensity ◽  
Intensity Analysis ◽  
Hydrogen Migration

Resonance Raman Intensity Analysis of Merocyanine Dimers in Solution†

2004 ◽  
Vol 108 (29) ◽  
pp. 10284-10294 ◽  
Author(s):  
Weinan Leng ◽  
Frank Würthner ◽  
Anne Myers Kelley
Keyword(s):  
Resonance Raman ◽  
Raman Intensity ◽  
Intensity Analysis
Sign in / Sign up

Export Citation Format

Share Document