Three-center versus four-center elimination in photolysis of vinyl fluoride and vinyl bromide at 193 nm: Bimodal rotational distribution of HF and HBr (v⩽5) detected with time-resolved Fourier transform spectroscopy

2001 ◽  
Vol 114 (17) ◽  
pp. 7396-7406 ◽  
Author(s):  
Shiaw-Ruey Lin ◽  
Shih-Che Lin ◽  
Yu-Chang Lee ◽  
Yung-Ching Chou ◽  
I-Chia Chen ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Fourier Transform Spectroscopy ◽  
Time Resolved ◽  
Vinyl Bromide ◽  
Vinyl Fluoride ◽  
Rotational Distribution ◽  
193 Nm

Photodissociation Dynamics of Vinyl Chloride Investigated with a Pulsed Slit-Jet and Time-Resolved Fourier-Transform Spectroscopy

2004 ◽  
Vol 57 (12) ◽  
pp. 1161 ◽  
Author(s):  
Mohammed Bahou ◽  
Yuan-Pern Lee
Keyword(s):  
Fourier Transform ◽  
Vinyl Chloride ◽  
Flow System ◽  
Supersonic Jet ◽  
Infrared Emission ◽  
Time Resolved ◽  
Type Distribution ◽  
Trajectory Calculations ◽  
Rotational Distribution ◽  
193 Nm

Following photodissociation of vinyl chloride seeded in a He supersonic jet at 193 nm, rotationally resolved infrared emission of HCl (v) are recorded to yield nascent rotational and vibrational distributions. Preliminary results show that the rotational distribution of HCl free from rotational quenching deviates slightly from Boltzmann-type distribution and agrees well with trajectory calculations; a portion of the low-J component observed previously in a flow system is attributed to quenching. The implications for photodissociation dynamics are discussed.

Sign in / Sign up

Export Citation Format

Share Document