Perturbation-allowed rotational transitions and A1–A2 splitting transitions in the ground, v2=1 and v4=1 vibrational states of SbH3 observed by microwave Fourier transform spectroscopy: Extension of the effective hyperfine Hamiltonian

2001 ◽  
Vol 114 (8) ◽  
pp. 3508-3523 ◽  
Author(s):  
H. Harder ◽  
C. Gerke ◽  
L. Fusina
1988 ◽  
Vol 43 (8-9) ◽  
pp. 755-757 ◽  
Author(s):  
N. Heineking ◽  
M. Andolfatto ◽  
C. Kruse ◽  
W. Eberstein ◽  
H. Dreizler

Abstract Employing the high resolution of microwave Fourier transform spectroscopy, we investigated the lowest rotational transitions of fluoro-, bromo-, and iodoacetylene-d. Along with the rotational, centrifugal distortion, halogen nuclear quadrupole, and halogen spin-rotation coupling constants, we determined the deuterium quadrupole coupling constants of bromo-and iodoacetylene-d. For fluoroacetylene-d, we redetermined the deuterium nuclear quadrupole coupling constants with higher accuracy.


1982 ◽  
Vol 37 (1) ◽  
pp. 58-63 ◽  
Author(s):  
G. Bestmann ◽  
H. Dreizler

Abstract In memory of W. H. We discuss the features of a microwave Fourier transform spectrometer in the X-and Ku-band as applied to the investigation of the hyperfine structure of rotational transitions. The Nitrogen-hyperfine structure of vinylisocyanide was measured and analysed.


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