Role of the energy transfer in the optical properties of undoped and Er-doped interacting Si nanocrystals

2001 ◽  
Vol 89 (1) ◽  
pp. 264-272 ◽  
Author(s):  
Francesco Priolo ◽  
Giorgia Franzò ◽  
Domenico Pacifici ◽  
Vincenzo Vinciguerra ◽  
Fabio Iacona ◽  
...  
2005 ◽  
Vol 19 (15n17) ◽  
pp. 2598-2603
Author(s):  
KIMIHISA MATSUMOTO ◽  
KENJI IMAKITA ◽  
MINORU FUJII ◽  
SHINJI HAYASHI

Photoluminescence (PL) properties of Er and Si nanocrystals co-doped SiO 2 films are studied in a wide Er concentration range. In the Er concentration range of less than 3 at%, Er 3+ was excited by the energy transfer from Si nanocrystals. Above this concentration, Si nanocrystals and Er do not exist independently but amorphous or crystallin alloys of Si-Er-O are formed. In this region Er can be excited only by directly absorbed excitation light. The highest PL intensity is observed in the Er concentration range where an amorphous alloy of Si-Er-O is formed.


2011 ◽  
Vol 35 (1) ◽  
pp. 15-27
Author(s):  
Zoran Ivić ◽  
Željko Pržulj

Adiabatic large polarons in anisotropic molecular crystals We study the large polaron whose motion is confined to a single chain in a system composed of the collection of parallel molecular chains embedded in threedimensional lattice. It is found that the interchain coupling has a significant impact on the large polaron characteristics. In particular, its radius is quite larger while its effective mass is considerably lighter than that estimated within the one-dimensional models. We believe that our findings should be taken into account for the proper understanding of the possible role of large polarons in the charge and energy transfer in quasi-one-dimensional substances.


Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2349
Author(s):  
Alain Salvador Conejo-Dávila ◽  
Marco Armando Moya-Quevedo ◽  
David Chávez-Flores ◽  
Alejandro Vega-Rios ◽  
Erasto Armando Zaragoza-Contreras

The development of anilinium 2-acrylamide-2-methyl-1-propanesulfonate (Ani-AMPS) monomer, confirmed by 1H NMR, 13C NMR, and FTIR, is systematically studied. Ani-AMPS contains two polymerizable functional groups, so it was submitted to selective polymerization either by free-radical or oxidative polymerization. Therefore, poly(anilinium 2-acrylamide-2-methyl-1-propanesulfonic) [Poly(Ani-AMPS)] and polyaniline doped with 2-acrylamide-2-methyl-1-propanesulfonic acid [PAni-AMPS] can be obtained. First, the acrylamide polymer, poly(Ani-AMPS), favored the π-stacking of the anilinium group produced by the inter- and intra-molecular interactions and was studied utilizing 1H NMR, 13C NMR, FTIR, and UV-Vis-NIR. Furthermore, poly(Ani-AMPS) fluorescence shows quenching in the presence of Fe2+ and Fe3+ in the emission spectrum at 347 nm. In contrast, the typical behavior of polyaniline is observed in the cyclic voltammetry analysis for PAni-AMPS. The optical properties also show a significant change at pH 4.4. The PAni-AMPS structure was corroborated through FTIR, while the thermal properties and morphology were analyzed utilizing TGA, DSC (except PAni-AMPS), and FESEM.


2021 ◽  
Vol 103 (17) ◽  
Author(s):  
P. P. Abrantes ◽  
G. Bastos ◽  
D. Szilard ◽  
C. Farina ◽  
F. S. S. Rosa

2021 ◽  
Author(s):  
Alagan Muthurasu ◽  
V GANESH

Carbon dots (CDs) exhibiting fluorescence property are generally derived from carbonaceous materials and possessing ultra small size with various exciting physical, chemical and photo-properties that have been used in many...


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