Solid‐State NMR Reveals Key Structural Features of Membrane Transport Proteins

Physics Today ◽  
2000 ◽  
Vol 53 (9) ◽  
pp. 19-22
Author(s):  
Charles Day
1991 ◽  
Vol 6 (3) ◽  
pp. 233-237 ◽  
Author(s):  
Hans Kiefer ◽  
Barbara Klee ◽  
Edgar John ◽  
York-Dieter Stierhof ◽  
Fritz Jähnig

2020 ◽  
Author(s):  
Jeongjae Lee ◽  
Woocheol Lee ◽  
Keehoon Kang ◽  
Takhee Lee ◽  
Sung Keun Lee

Application of two-dimensional (2D) organic-inorganic hybrid halide perovskites for optoelectronic devices requires detailed understanding of the local structural features including the Pb-I bonding in the 2D layers and the capping ligand-perovskite interaction. In this study, we show that <sup>1</sup>H and <sup>207</sup>Pb solid-state Nuclear Magnetic Resonance (NMR) spectroscopy can serve as a non-invasive and complementary technique to quantify the composition and to probe the local structural features of 2D Ruddlesden-Popper phase BA<sub>2</sub>MA<i><sub>n</sub></i><sub>-1</sub>Pb<i><sub>n</sub></i>I<sub>3<i>n</i>+1</sub> (<i>n</i>=1-4) with butylammonium (BA) spacers. <sup>207</sup>Pb echo and <sup>1</sup>H-detected <sup>207</sup>Pb→<sup>1</sup>H heteronuclear correlation (HETCOR) experiments enables layer-by-layer structural detection of 2D halide perovskites. We show that the observed correlation between <sup>207</sup>Pb NMR shifts and mean Pb-I bond lengths around each Pb site allows us to probe the local bonding environment of Pb via its <sup>207</sup>Pb NMR shift. We envisage that this technique will be vital for better understanding the materials properties as determined by the local atomistic environments in multi-dimensional halide perovskites.


2016 ◽  
Vol 150 (4) ◽  
pp. S113-S114 ◽  
Author(s):  
Nicholas W. Baetz ◽  
Akshita Gupta ◽  
Anirudh Kapoor ◽  
Olga Kovbasnjuk ◽  
Jerrold Turner ◽  
...  

Science ◽  
1968 ◽  
Vol 162 (3854) ◽  
pp. 632-637 ◽  
Author(s):  
A. B. Pardee

1994 ◽  
pp. 26
Author(s):  
Fritz Jähnig ◽  
Barbara Klee ◽  
Hans Kiefer ◽  
Edgar John

Sign in / Sign up

Export Citation Format

Share Document