An improved compressible electrostatic continuum model for solvation in supercritical water

1999 ◽  
Author(s):  
Susan C. Tucker ◽  
James T. Vivian
Keyword(s):  
Supercritical Water ◽  
Continuum Model

PENGGUNAAN AIR SUPER KRITIS PADA DEPOLIMERISASI NYLON-12 (BATCH PROCESS)

2018 ◽  
Vol 5 (3) ◽  
Author(s):  
Mohamad Yusman
Keyword(s):  
Supercritical Water ◽  
Scale Up ◽  
Experimental Studies ◽  
Reaction System ◽  
Batch Process ◽  
Chemical Recycling ◽  
Water Decomposition ◽  
Product Distributions ◽  
New Process ◽  
Nylon 12

Water at the supercritical state is a new process for the chemical recycling. At this thermodynamic state i.e. Pc = 218 atmospheres and Tc = 374oC , water behaves very differently from its everyday temperament and it is a very good solvent for organic components. Experimental studies show that supercritical water can decompose hydrocarbons/polymers and produce useful products like 2-Azacyclotridecanone /lactam-1 from Nylon-12 (batch process). The decomposition process itself was carried out in batch reaction system in order to get more information about product distributions, time dependence, and scale-up possibilities.Keywords: supercritical water, decomposition, batch, polymer, hydrocarbon

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