Effect of tolerance factor and local distortion on magnetic properties of the perovskite manganites

1999 ◽  
Vol 75 (8) ◽  
pp. 1146-1148 ◽  
Author(s):  
J. P. Zhou ◽  
J. T. McDevitt ◽  
J. S. Zhou ◽  
H. Q. Yin ◽  
J. B. Goodenough ◽  
...  
2015 ◽  
Vol 24 (5) ◽  
pp. 057501 ◽  
Author(s):  
Xue Hou ◽  
Deng-Hui Ji ◽  
Wei-Hua Qi ◽  
Gui-De Tang ◽  
Zhuang-Zhi Li

2018 ◽  
Vol 460 ◽  
pp. 501-508 ◽  
Author(s):  
S.Q. Li ◽  
L.Q. Wu ◽  
W.H. Qi ◽  
X.S. Ge ◽  
Z.Z. Li ◽  
...  

Materials ◽  
2018 ◽  
Vol 11 (7) ◽  
pp. 1204 ◽  
Author(s):  
Parvathy Anitha Sukkurji ◽  
Alan Molinari ◽  
Christian Reitz ◽  
Ralf Witte ◽  
Christian Kübel ◽  
...  

Chemical doping via insertion of ions into the lattice of a host material is a key strategy to flexibly manipulate functionalities of materials. In this work, we present a novel case study on the topotactic insertion of fluoride ions into oxygen-deficient ferromagnetic thin films of La0.74Sr0.26MnO3−δ (LSMO) epitaxially grown onto single-crystal SrTiO3 (STO) substrates. The effect of fluorination on the film structure, composition, and magnetic properties is compared with the case of oxygen-deficient and fully-oxidized LSMO films. Although incorporation of F− anions does not significantly alter the volume of the LSMO unit cell, a strong impact on the magnetic characteristics, including a remarkable suppression of Curie temperature and saturation magnetization accompanied by an increase in magnetic coercivity, was found. The change in magnetic properties can be ascribed to the disruption of the ferromagnetic exchange interactions along Mn-anion-Mn chains driven by F− doping into the LSMO lattice. Our results indicate that F− doping is a powerful means to effectively modify the magnetic functional properties of perovskite manganites.


2014 ◽  
Vol 50 (7) ◽  
pp. 1-4 ◽  
Author(s):  
Yuk-Kwan Chan ◽  
Sheung-Mei Ng ◽  
Wang-Cheung Wong ◽  
Chi-Wah Leung

2015 ◽  
Vol 754-755 ◽  
pp. 757-761
Author(s):  
Abdullah Chik ◽  
S. Saad ◽  
Cheow Keat Yeoh ◽  
R.M. Zaki ◽  
F. Che Pa

The electronic structure of the perovskite manganites AlMnO3cubic crystal was presented. The calculations were made within density functional theory and PBE exchange correlations energy approximation. It was found that the crystal exhibit covalent bonding between Mn and O with superexchange mechanism. At groundstate, AlMnO3stabilizes in antiferromagnetic structure with semi metallic like nature at the ground state.


2012 ◽  
Vol 26 (08) ◽  
pp. 1250049
Author(s):  
RENWEN LI ◽  
LI PI ◽  
WEI TONG ◽  
LEI ZHANG ◽  
LANGSHENG LING ◽  
...  

Structural and magnetic properties of Bi0.5 Ca0.5-xBaxMnO3 (x = 0, 0.03, 0.05, 0.07 and 0.10) samples with charge ordering (CO) state and C-type antiferromagnetic (AFM) magnetic structure have been studied systematically. With increasing Ba-doping level, both CO and AFM are weakened. From the micro-magnetic analysis, we clarify the ambiguity about the Néel temperature TN in bismuth-based perovskite manganites. We find that the paramagnetic (PM)-CO/AFM transition temperature TCO at high temperature is the onset temperature of the PM–AFM transition, while customarily so-called TN at low temperature indicates the finish of the PM–AFM transition. Both the macro- and micro-magnetic data show that, in all the samples, only AFM state coexists with PM matrix below CO transition and above TN, while AFM state coexists with ferromagnetic (FM) state and PM state at lower temperature below TN.


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